Preparation and electrochemical characterization of nanocrystalline Li[Li0.12Ni0.32Mn0.56]O2 pyrolyzed from polyacrylate salts

被引：6

作者：

Yu, LH ^{[1
]}

Cao, YL ^{[1
]}

Yang, HX ^{[1
]}

Ai, XP ^{[1
]}

Ren, YY ^{[1
]}

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2004年 / 88卷 / 2-3期

关键词：

cathode material; layered compound; lithium-ion battery;

D O I：

10.1016/j.matchemphys.2004.07.023

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A nanocrystalline Li[Li0.12Ni0.32Mn0.56]O-2 powder was synthesized by a pyrolysis method using polyacrylate salts as the precursor compounds. XRD and TEM results demonstrated that the Li[Li0.12Ni0.32Mn0.56]O-2 powder has a layered structure as alpha-NaFeO2 and has an average particle size of 50-70 nm. The charge-discharge experiments show that the Li[Li0.12Ni0.32Mn0.56]O-2 electrode can deliver a reversible, capacity of similar to140mA h g(-1) cycling at 2.5-4.5 V and can still remain 94% of its initial capacity after 10 cycles, showing a great promise for future applications. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：353 / 356

页数：4

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