Bi-functional starch composites prepared by γ-irradiation for removal of anionic and cationic dyes from aqueous solutions

被引:38
作者
Hashem, A.
Abdel-Halim, E. S.
Sokker, H. H.
机构
[1] Natl Res Ctr, Text Res Div, Cairo, Egypt
[2] Natl Ctr Radiat & Technol, Cairo, Egypt
关键词
adsorption; anionic and cationic dyes; bifunctional; starch hydrogel;
D O I
10.1080/03602550600950364
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Bifunctional starch composites were prepared by gamma-induced grafting of acrylamide (Aam) and acrylic acid (AA) onto maize starch. The prepared composites were characterized by FTIR spectroscopy and scanning electron microscope (SEM). The feasibility of these composites to remove anionic dyes, direct blue 21 (D. Blue 21) and direct brown 2 (D. Brown 2) and a cationic dye, methylene blue (MB) were examined. Factors affecting adsorption of anionic and cationic dyes onto these starch composites were studied. These factors were radiation dose, agitation time, adsorbent and adsorbate concentrations. Prepared composites were effectively used in adsorption of D. Blue 2, D. Brown 2 and MB from aqueous solutions. The Adsorption data of both D. Blue 21 and D. Brown 2 complied with the Langmuir and Freundlich isotherms.
引用
收藏
页码:71 / 77
页数:7
相关论文
共 24 条
[1]  
ABDELBARRY EM, 1997, HDB ENG POLYM MAT
[2]   Use of cellulose-based wastes for adsorption of dyes from aqueous solutions [J].
Annadurai, G ;
Juang, RS ;
Lee, DJ .
JOURNAL OF HAZARDOUS MATERIALS, 2002, 92 (03) :263-274
[3]   Syntheses and characterisation of graft copolymers of maize starch and methacrylonitrile [J].
Athawale, VD ;
Lele, V .
CARBOHYDRATE POLYMERS, 2000, 41 (04) :407-416
[4]   Cloth filter for recovery of uranium from radioactive waste [J].
Badawy, SM ;
Sokker, HH ;
Othman, SH ;
Hashem, A .
RADIATION PHYSICS AND CHEMISTRY, 2005, 73 (02) :125-130
[5]   Syntheses and photobiodegradable properties of graft copolymers of vinyl ketones and starch [J].
Choi, WM ;
Jung, ID ;
Kwon, SK ;
Ha, CS ;
Cho, WJ .
POLYMER DEGRADATION AND STABILITY, 1998, 61 (01) :15-20
[6]   Starch-based biodegradable hydrogels with potential biomedical applications as drug delivery systems [J].
Elvira, C ;
Mano, JF ;
San Román, J ;
Reis, RL .
BIOMATERIALS, 2002, 23 (09) :1955-1966
[7]  
Freundlich H., 1907, PHYS CHEM, V57, P384
[8]   PORE- AND SOLID-DIFFUSION KINETICS IN FIXED-BED ADSORPTION UNDER CONSTANT-PATTERN CONDITIONS [J].
HALL, KR ;
EAGLETON, LC ;
ACRIVOS, A ;
VERMEULEN, T .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1966, 5 (02) :212-+
[9]   Quaternization of cotton stalks and palm tree particles for removal of acid dye from aqueous solutions [J].
Hashem, A ;
Aly, AA ;
Aly, AS ;
Hebeish, A .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2006, 45 (03) :389-394
[10]   Preparation and utilization of cationized sawdust [J].
Hashem, A ;
Aly, AA ;
Aly, AS .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2006, 45 (03) :395-401