A strategy to detect the effect of electrode defects on the electrical reliability in multilayer ceramic capacitors

被引:21
作者
Zhang, Weichen [1 ]
Zhu, Chaoqiong [1 ]
Hui, Kezhen [1 ]
Zhao, Peiyao [1 ]
Guo, Limin [2 ]
Cai, Ziming [3 ]
Li, Longtu [1 ]
Wang, Xiaohui [1 ]
机构
[1] Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
[2] Beijing Univ Posts & Telecommun, Sch Sci, Beijing 100876, Peoples R China
[3] China Univ Min & Technol, Sch Mat Sci & Phys, Xuzhou 221116, Peoples R China
基金
中国国家自然科学基金;
关键词
MLCC; Electrode quality; Reliability; FEM; KPFM; FIELD ENHANCEMENT; RESISTANCE DEGRADATION; PART II; BATIO3;
D O I
10.1016/j.mtener.2022.101022
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Multilayer ceramic capacitors (MLCCs) are indispensable devices to electronic industry due to their high capacitance and good temperature stability, which shares the largest market of passive electronic devices. However, electrode defects could adversely influence the reliability, especially for thin-layer MLCCs. It is important to understand the internal relationship between electrode quality and reliability. In this work, finite element method simulation and Kelvin probe force microscopy measurement are introduced to investigate the surface electric field distribution on the cross section of MLCCs. Successively-enhanced local electric field concentration could be detected in the vicinity of electrode roughness, electrode discontinuity, and pores based on both simulation and experimental methods. In addition, probability density of electric field curves and critical intensification factor are calculated to quantitatively characterize the electric field distribution. Electrical measurement results have revealed that MLCCs with superior electrode quality exhibit high reliability, which is further verified by studying the standard MLCCs with nearly perfect electrodes. This work innovatively utilized the Kelvin probe force microscopy test and statistical quantitative characterization of electric field distribution, which may serve as the common approaches in MLCC industries to help understand the mechanism of electrical failure.(c) 2022 Elsevier Ltd. All rights reserved.
引用
收藏
页数:9
相关论文
共 41 条
[1]   High-temperature lead-free multilayer ceramic capacitors with ultrahigh energy density and efficiency fabricated via two-step sintering [J].
Cai, Ziming ;
Zhu, Chaoqiong ;
Wang, Hongxian ;
Zhao, Peiyao ;
Chen, Lingling ;
Li, Longtu ;
Wang, Xiaohui .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (24) :14575-14582
[2]   Thermal-mechanical-electrical coupled design of multilayer energy storage ceramic capacitors [J].
Cai, Ziming ;
Wang, Xiaohui ;
Luo, Bingcheng ;
Wu, Longwen ;
Li, Longtu .
CERAMICS INTERNATIONAL, 2017, 43 (15) :12882-12887
[3]   Dc-electrical degradation of the BT-based material for multilayer ceramic capacitor with Ni internal electrode: Impedance analysis and microstructure [J].
Chazono, H ;
Kishi, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2001, 40 (9B) :5624-5629
[4]   Effect of TiO2 doped Ni electrodes on the dielectric properties and microstructures of (Ba0.96Ca0.04)(Ti0.85Zr0.15)O3 multilayer ceramic capacitors [J].
Chiang, Chen-Su ;
Lee, Ying-Cliieh ;
Shiao, Fu-Thang ;
Lee, Wen-Hsi ;
Hennings, Detlev .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2012, 32 (04) :865-873
[5]   Finite element modeling on the effect of intra-granular porosity on the dielectric properties of BaTiO3 MLCCs [J].
Dale, Graham ;
Strawhorne, Maureen ;
Sinclair, Derek C. ;
Dean, Julian S. .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2018, 101 (03) :1211-1220
[6]   Grain size effect on electrical and reliability characteristics of modified fine-grained BaTiO3 ceramics for MLCCs [J].
Gong, Ling ;
Wang, Xiaohui ;
Zhang, Shaopeng ;
Wen, Hai ;
Li, Longtu .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2014, 34 (07) :1733-1739
[7]   Design, fabrication and dielectric properties in core-double shell BaTiO3-based ceramics for MLCC application [J].
Hao, Hua ;
Liu, Mengying ;
Liu, Hanxing ;
Zhang, Shujun ;
Shu, Xin ;
Wang, Ting ;
Yao, Zhonghua ;
Cao, Minghe .
RSC ADVANCES, 2015, 5 (12) :8868-8876
[8]   Electric field enhancement in ceramic capacitors due to interface amplitude roughness [J].
Heath, James P. ;
Harding, John H. ;
Sinclair, Derek C. ;
Dean, Julian S. .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2019, 39 (04) :1170-1177
[9]   Theoretical Study on Interactions between Oxygen Vacancy and Doped Rare-Earth Elements in Barium Titanate [J].
Honda, Atsushi ;
Higai, Shin'ichi ;
Motoyoshi, Yasuhiro ;
Wada, Nobuyuki ;
Takagi, Hiroshi .
JAPANESE JOURNAL OF APPLIED PHYSICS, 2011, 50 (09)
[10]   Perspectives and challenges in multilayer ceramic capacitors for next generation electronics [J].
Hong, Kootak ;
Lee, Tae Hyung ;
Suh, Jun Min ;
Yoon, Seok-Hyun ;
Jang, Ho Won .
JOURNAL OF MATERIALS CHEMISTRY C, 2019, 7 (32) :9782-9802