Dielectric and piezoelecrtic properties of lead-free (Na0.5Bi0.5)TiO3-NaNbO3 ceramics

被引:190
作者
Li, YM
Chen, W [1 ]
Zhou, J
Xu, Q
Sun, H
Xu, RX
机构
[1] Wuhan Univ Technol, Inst Mat Sci & Engn, Wuhan 430070, Hubei, Peoples R China
[2] Jingdezhen Ceram Inst, Jingdezhen 333001, Peoples R China
来源
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 2004年 / 112卷 / 01期
基金
中国国家自然科学基金;
关键词
dielectric properties; piezoelectric properties; Na0.5Bi0.5TiO3; perovskite; relaxor;
D O I
10.1016/j.mseb.2004.04.019
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, lead-free [Na0.5(1+x)Bi0.5(1-x)](Ti(1-x)Nbx)O-3 (x= 0-0.08) ceramics were fabricated by using conventional ceramic technique. The phase structure of the solid solution has been determined by the X-ray diffraction. Dielectric study revealed that the dielectric relaxor behavior becomes more obviously by doping of NaNbO3 into (Na0.5Bi0.5)TiO3. The samples in the composition range from x = 0.01 to 0.02 exhibited excellent electrical properties, piezoelectric constant d(33) = 80-88 pC/N; electromechanical planar coupling coefficients k(p) = 17.92%. The results show that the [Na0.5(1+x)Bi0.5(1-x)](Ti(1-x)Nbx)O-3 ceramics are one of the promising lead-free materials for ultrasonic transducer applications. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:5 / 9
页数:5
相关论文
共 23 条
[1]  
CROSS LE, 1987, FERROELECTRICS, V76, P241, DOI 10.2109/jcersj.99.829
[2]   Processing and electromechanical properties of (Bi0.5Na0.5)((1-1.5x))LaxTiO3 ceramics [J].
Herabut, A ;
Safari, A .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1997, 80 (11) :2954-2958
[3]  
Hidehiro O., 1998, JPN J APPL PHYS, V37, P5410
[4]  
Jaffe B., 1971, Piezoelectric Ceramics
[5]   Ferroelectric and piezoelectric properties of kNbO3 ceramics containing small amounts of LaFeO3 [J].
Kakimoto, K ;
Masuda, I ;
Ohsato, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2003, 42 (9B) :6102-6105
[6]   High-frequency and high-temperature electromechanical performances of new PZT-PNN piezoceramics [J].
Levassort, F ;
Tran-Huu-Hue, P ;
Ringaard, E ;
Lethiecq, M .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (10-11) :1361-1365
[7]   USEFUL FORMULAS FOR PIEZOELECTRIC CERAMIC RESONATORS AND THEIR APPLICATION TO MEASUREMENT OF PARAMETERS [J].
ONOE, M ;
JUMONJI, H .
JOURNAL OF THE ACOUSTICAL SOCIETY OF AMERICA, 1967, 41 (4P2) :974-&
[8]   Variations of structure and dielectric properties on substituting A-site cations for Sr2+ in (Na1/2Bi1/2)TiO3 [J].
Park, SE ;
Hong, KS .
JOURNAL OF MATERIALS RESEARCH, 1997, 12 (08) :2152-2157
[9]  
Ralph Wyckoff W.G., 1964, CRYSTAL STRUCTURES, V2
[10]   New lead-free relaxor ceramics derived from BaTiO3 by cationic heterovalent substitutions in the 12 CN crystallographic site [J].
Ravez, J ;
Simon, A .
SOLID STATE SCIENCES, 2000, 2 (05) :525-529