Structural diversification of coordination assemblies of MII-dca - Hydroxylpyridine (dca = Dicyanamide)

被引：13

作者：

Zheng, Ling Ling ^{[1
]}

Zhou, Chang Xia ^{[2
]}

Hu, Sheng ^{[2
]}

Zhou, Ai Ju ^{[3
]}

机构：

[1] Guangzhou Vocat Coll Technol & Business, Guangzhou 511442, Guangdong, Peoples R China

[2] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China

[3] Guangzhou Univ, Sch Chem & Chem Engn, Guangzhou 510006, Guangdong, Peoples R China

来源：

POLYHEDRON | 2016年 / 104卷

关键词：

Hydroxylpyridine; Dicyanamide; Coordination polymers; Hydrogen bonding; Magnetic property; DEPROTONATED 3-HYDROXYPYRIDINE LIGANDS; BCU-TYPE TOPOLOGY; CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; POLYMERS; 2D; COMPLEXES; CLUSTERS; BEHAVIOR;

D O I：

10.1016/j.poly.2015.11.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three coordination polymers [Mn(dca)(2)(2-pyEtOH)(n) (1), [Co(dca)(MeOH)(2)(3-PyO)(3-PyOH)n (2), [Zn (dca) (3-py0)n(,) (3) (2-pyEtOH = 2-ethanolpyridine; 3-pyOH = 3-hydroxypyridine) have been synthesized and their crystal structures determined. In the resulting crystalline materials, dca generally display the mu(1,5) bridging fashion. 2-pyEtOH is used as bidentate terminal ligand in 1; 3-pyOH is coordinated to Coll in monodentate style in 2; while 3-pyOH is used as a bridging ligand in 3, affording diverse two-, one and three dimensional coordination networks. 3 shows rare eight coordinated bcu-type topology. Meanwhile, different hydrogen bonding interactions are observed in 1 and 2. For 1 and 2, weak antiferromagnetic interactions are observed. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：91 / 98

页数：8

共 35 条

[1]

[Anonymous], 1997, SHELXTL 97 PROGRAM C

[2]

[Anonymous], SOFTW PACK SMART SAI

[3] Novel three-dimensional cage assembly of a μ4-carbonato-bridged cobalt(II) compound [Co2(bpm)(H2O)2(CO3)(OH)]NO3•4H2O [J].

Armentano, D ;

De Munno, G ;

Lloret, F ;

Julve, M .

INORGANIC CHEMISTRY, 1999, 38 (16) :3744-+

[4] Structure and magnetism of coordination polymers containing dicyanamide and tricyanomethanide [J].

Batten, SR ;

Murray, KS .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :103-130

[5]

Carlin R.L., 1986, Magnetochemistry

[6] Synthesis, crystal structure, thermal behaviour and magnetic properties of a novel one-dimensional copper(II) complex containing neutral and deprotonated 3-hydroxypyridine ligands [J].

Castillo, O ;

Luque, A ;

Iglesias, S ;

Vitoria, P ;

Román, P .

NEW JOURNAL OF CHEMISTRY, 2000, 24 (10) :771-775

[7] Discrete 0D and polymeric 2D and 3D derivatives assembled from [(CuL)2Zn]2+ and dicyanamide blocks (H2L = salen type Schiff bases): Genuine supramolecular isomers with distinct topologies [J].

Das, Lakshmi Kanta ;

Kirillov, Alexander M. ;

Ghosh, Ashutosh .

CRYSTENGCOMM, 2014, 16 (14) :3029-3039

[8] A new two-dimensional manganese(II)-azide polymer. Synthesis, structure and magnetic properties of [{Mn(minc)(2)(N-3)(2)}(n)] (minc equals methyl isonicotinate) [J].

Escuer, A ;

Vicente, R ;

Goher, MAS ;

Mautner, FA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (22) :4431-4434

[9] Unprecedented strong blue fluorescent cadmium(II) coordination polymer based on neutral and deprotonated 3-hydroxypyridine ligands [J].

Gao, S ;

Lu, ZZ ;

Huo, LH ;

Zhao, H ;

Zhao, JG .

INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (01) :96-98

[10] Synthesis, crystal structure and magnetic behavior of three polynuclear complexes:: [Co(pyo)2(dca)2]n, [Co3(ac)4(bpe)3(dca)2]n and [{Co(male)(H2O)2}(H2O)]n [pyo, pyridine-N-oxide; dca, dicyanamide; ac, acetate; bpe, 1,2-bis-(4-pyridyl)ethane and male, maleate] [J].

Ghoshal, D ;

Mostafa, G ;

Maji, TK ;

Zangrando, E ;

Lu, TH ;

Ribas, J ;

Chaudhuri, NR .

NEW JOURNAL OF CHEMISTRY, 2004, 28 (10) :1204-1213

← 1 2 3 4 →