Utilization of powdered EPDM scrap in EPDM compound

被引:13
作者
Jacob, C [1 ]
Bhowmick, AK [1 ]
De, PP [1 ]
De, SK [1 ]
机构
[1] Indian Inst Technol, Ctr Rubber Technol, Kharagpur 721302, W Bengal, India
来源
RUBBER CHEMISTRY AND TECHNOLOGY | 2003年 / 76卷 / 01期
关键词
D O I
10.5254/1.3547740
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Processability, curing characteristics and vulcanizate properties of EPDM compounds containing ground waste EPDM (W-EPDM) have been studied. Ground waste was prepared from factory scraps, using a mechanical grinder with silicon carbide abrasive wheel rotating at 2950 rpm. The particle size shows a range between 2 and 50 mum, with an average size of 10 mum. Particle surface seems to be rough and convoluted and mild oxidation during the abrasion enhances the aggregation of particles. Mooney scorch time and the maximum rheometric torque of the EPDM compound decrease gradually with increasing W-EPDM content. Migration of curatives between the virgin rubber and waste rubber phases is believed to be the reason for the variation in the curing behavior. The processability of the EPDM compound shows improvement on addition of W-EPDM (that is, both die swell and extrudate distortion are less). The vulcanizate properties of the W-EPDM-filled EPDM compounds reveal the reinforcing nature of the ultrafine W-EPDM particles. Comparison of W-EPDM with an inert filler like precipitated CaCO3 in an EPDM compound reveals the potential of W-EPDM as a cheap filler in EPDM compounds. It Is also found that W-EPDM can be incorporated into the window seal compound formulation and the drop in properties even at 100 phr of W-EPDM is within acceptable limit, thus providing a scope for on-site recycling of EPDM.
引用
收藏
页码:36 / 59
页数:24
相关论文
共 42 条
[1]   THE POSSIBILITY OF USING GRAFTED WASTE RUBBER [J].
ADAM, G ;
SEBENIK, A ;
OSREDKAR, U ;
RANOGAJEC, F ;
VEKSLI, Z .
RUBBER CHEMISTRY AND TECHNOLOGY, 1991, 64 (02) :133-138
[2]  
ALMALAIKA S, 1993, POLYM DEGRAD STABIL, V26, P31
[3]  
[Anonymous], 1998, RUBBER WORLD
[4]  
[Anonymous], 1976, RUBBER CHEM TECHNOL
[5]  
BAUMANN BD, 1995, RUBBER WORLD, V212, P30
[6]   EFFECT OF CURING SYSTEMS ON POLYMER FILLER INTERACTION, TECHNICAL PROPERTIES AND FRACTURE MODE OF CARBOXYLATED NITRILE RUBBER [J].
CHAKRABORTY, SK ;
DE, SK .
POLYMER, 1983, 24 (08) :1055-1062
[7]  
DIERKES IW, 1996, RUBBER WORLD, V214, P25
[8]  
FOLDI AP, 1976, RUBBER CHEM TECHNOL, V49, P233
[9]  
Fujimoto K., 1981, INT POLYM SCI TECHNO, V30, P29
[10]  
Fujimoto K., 1981, INT POLYM SCI TECHN, V8, P25