Room temperature synthesis, crystal structure and selected properties of the new compound [Mn2(bipy)4SbS4](ClO4)

被引:6
作者
Anderer, Carolin [1 ]
Naether, Christian [1 ]
Bensch, Wolfgang [1 ]
机构
[1] Univ Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany
来源
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2016年 / 71卷 / 05期
关键词
crystal structure; solvothermal syntheses; thioantimonates; STRUCTURE-DIRECTING AGENTS; SOLVOTHERMAL SYNTHESES; TRANSITION-METAL; THERMAL-STABILITY; ANTIMONY-SULFIDE; 1ST EXAMPLE; LAYERED THIOANTIMONATE(III); HYDROTHERMAL SYNTHESIS; MN-2(L)SB2S5 FAMILY; COMPLEXES;
D O I
10.1515/znb-2015-0205
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The new compound [Mn-2(bipy)(4)SbS4](ClO4) was prepared by a new synthetic route for the preparation of thioantimonates(V) that can be used even at room temperature. Mixing aqueous solutions of [Mn(bipy)(3)] (ClO4)(2) and Na3SbS4 center dot 9H(2)O leads to immediate crystallization of the pure compound. In the structure an SbS43- anion acts as a tetradentate bridge connecting two Mn2+ cations of [Mn(bipy)(3)](2+) complexes (bipy = 2,2'-bipyridine). The compound features a hitherto unknown [Mn-2(bipy)(4)SbS4](+) cation. Bipy ligands of adjacent cations are arranged parallel to each other leading to weak off-center parallel pi-pi interactions stabilizing the crystals. Magnetic measurements indicate weak antiferromagnetic exchange interactions between the Mn2+ centers.
引用
收藏
页码:395 / 401
页数:7
相关论文
共 78 条
[1]   A Strategy for the Preparation of Thioantimonates Based on the Concept of Weak Acids and Corresponding Strong Bases [J].
Anderer, Carolin ;
de Alarcon, Natalie Delwa ;
Naether, Christian ;
Bensch, Wolfgang .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (51) :16953-16959
[2]   Synthesis and crystal structure of the bi-metallic hybrid compound {Mn4(2,2′-bipyridine)2Sb4S10} [J].
Anderer, Carolin ;
Naether, Christian ;
Bensch, Wolfgang .
INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 46 :335-339
[3]  
[Anonymous], 2015, Acta Crystallogr., V71, P3
[4]   Photoinduced oxidation of [Mn(L)3]2+ and [Mn2O2(L)4]3+(L=2,2′- bipyridine and 4,4′-dimethyl-2,2′-bipyridine) with the [Ru(bpy)3]2+/-aryl diazonium salt system [J].
Baffert, C ;
Dumas, S ;
Chauvin, J ;
Leprêtre, JC ;
Collomb, MN ;
Deronzier, A .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2005, 7 (01) :202-210
[5]  
Bensch W, 1996, EUR J SOL STATE INOR, V33, P1149
[6]   Solvothermal synthesis of [Ni(C4H13N3)2]2Sb4S8:: the first compound with a cyclic [Sb4S8]4- anion [J].
Bensch, W ;
Näther, C ;
Stähler, R .
CHEMICAL COMMUNICATIONS, 2001, (05) :477-478
[7]  
Bensch W, 1997, EUR J SOL STATE INOR, V34, P457
[8]   A coordination chemistry approach towards ternary M/14/16 anions [J].
Dehnen, Stefanie ;
Melullis, Maike .
COORDINATION CHEMISTRY REVIEWS, 2007, 251 (9-10) :1259-1280
[9]   [Ni(phen)3]2Sb18S29: A Novel Three-Dimensional Framework Thioantimonate(III) Templated by [Ni(phen)3] Complexes [J].
Du, Ke-Zhao ;
Feng, Mei-Ling ;
Li, Long-Hua ;
Hu, Bing ;
Ma, Zu-Ju ;
Wang, Peng ;
Li, Jian-Rong ;
Wang, Yu-Long ;
Zou, Guo-Dong ;
Huang, Xiao-Ying .
INORGANIC CHEMISTRY, 2012, 51 (07) :3926-3928
[10]   Utility and synthetic uses of Mannich reaction: An efficient route for synthesis of thiadiazino-[1,3,5][3,2-a]benzimidazoles [J].
El-Wareth, A ;
Sarhan, AO ;
Abdel-Hafez, SH ;
El-Sherief, H ;
Aboel-Fadl, T .
SYNTHETIC COMMUNICATIONS, 2006, 36 (08) :987-996