Overshoot and oscillation in surface tension of gelatin solutions

被引:3
作者
Hyono, A
Sato, H
Matsubara, H
Okubo, M
Ohshima, H
机构
[1] Sci Univ Tokyo, Fac Pharmaceut Sci, Inst Colloid & Surface Sci, Noda, Chiba 2788510, Japan
[2] Kyoto Univ, Fac Engn, Grad Sch Polymer Chem, Katsuta, Kyoto 6158510, Japan
[3] Kobe Univ, Grad Sch Sci & Technol, Kobe, Hyogo 6578501, Japan
[4] Kyushu Univ, Fac Sci, Dept Chem, Fukuoka 8128581, Japan
关键词
surface tension; gelatin solutions; overshoot; oscillation;
D O I
10.1016/j.colsurfb.2004.09.001
中图分类号
Q6 [生物物理学];
学科分类号
071011 ;
摘要
The experimental data of the surface tension of aqueous gelatin solution reported by Sato and Ueberreiter [H. Sato, K. Ueberreiter, Macromol. Chem. 180 (1979) 829; H. Sato, K. Ueberreiter, Macromol. Chem. 180 (1979) 1107; H. Sato, K. Ueberreiter, ACS Polym. Preprints 20 (1979) 907] were analyzed with a theory of adsorption kinetics with time delay. It is found that the observed overshoot and oscillation of the surface tension are well explained by the present theory. The delay time and the rate constants of adsorption and desorption of gelatin molecules onto the air/gelatin solution interface have been evaluated. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:65 / 68
页数:4
相关论文
共 12 条
[1]   END-ATTACHING COPOLYMER ADSORPTION - KINETICS AND EFFECTS OF CHAIN ARCHITECTURE [J].
DORGAN, JR ;
STAMM, M ;
TOPRAKCIOGLU, C ;
JEROME, R ;
FETTERS, LJ .
MACROMOLECULES, 1993, 26 (20) :5321-5330
[2]   ADSORPTION-KINETICS OF END-ATTACHING TRIBLOCK COPOLYMERS [J].
DORGAN, JR ;
STAMM, M ;
TOPRAKCIOGLU, C .
POLYMER, 1993, 34 (07) :1554-1557
[3]   Overshoots of adsorption kinetics [J].
Filippov, LK ;
Filippova, NL .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 178 (02) :571-580
[4]   Non-Langmuir adsorption on planar surfaces: Nonlinear theory and experiment [J].
Filippova, NL .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 195 (01) :203-215
[5]   FURTHER-STUDIES ON MEMBRANE-TRANSPORT WITH TIME-DELAY [J].
OHSHIMA, H ;
KAMEI, M ;
KONDO, T .
BIOPHYSICAL CHEMISTRY, 1991, 41 (03) :301-305
[6]   MEMBRANE-TRANSPORT EQUATIONS WITH A TIME-DELAY - A MODEL FOR OVERSHOOT AND OSCILLATORY PERMEATION [J].
OHSHIMA, H ;
KONDO, T .
BIOPHYSICAL CHEMISTRY, 1989, 33 (03) :303-310
[7]   ADSORPTION-KINETICS WITH TIME-DELAY [J].
OHSHIMA, H ;
FUJITA, N ;
KONDO, T .
COLLOID AND POLYMER SCIENCE, 1992, 270 (07) :707-710
[8]   A theory of adsorption kinetics with time delay and its application to overshoot and oscillation in the surface tension of gelatin solution [J].
Ohshima, H ;
Sato, H ;
Matsubara, H ;
Hyono, A ;
Okubo, M .
COLLOID AND POLYMER SCIENCE, 2004, 282 (10) :1174-1178
[9]  
SATO H, 1979, MAKROMOL CHEM, V180, P829
[10]  
SATO H, 1979, MAKROMOL CHEM, V180, P1107