Hydrothermal assembly and structural characterization of an unprecedented one-dimensional chain constructed from nickel diphosphopentamolybdate clusters

被引：6

作者：

Bo, Q. B. ^{[1
]}

Sun, Z. X. ^{[1
]}

Sun, G. X. ^{[1
]}

Zhang, Z. W. ^{[1
]}

Chen, C. L. ^{[1
]}

Li, Y. X. ^{[1
]}

机构：

[1] Jinan Univ, Inst Chem & Chem Engn, Shandong 250022, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 03期

关键词：

nickel; phosphomolybdate; hybrid compound; hydrothermal synthesis; crystal structure;

D O I：

10.1080/00958970600763607

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel molybdenum phosphate complex, [Ni(1)(en)(2)(PO4)(2)Mo5O15][Ni(2)(en)(2-)(H2O)(2)] center dot H(2)en center dot 3H(2)O (1), has been synthesized under hydrothermal conditions. The complex was characterized by elemental analysis, FT-IR, DTA/TG and single crystal X-ray diffraction. The compound is orthorhombic, space group P2(1)2(1)2(1), with a = 12.580(3), b = 17.676(4), c = 17.969(4) angstrom, V = 3995.5(15) angstrom(3), Z = 4, and was refined to R-1 = 0.0301, wR(2) = 0.0715. It possesses an unprecedented one-dimensional chain structure constructed from molybdenum phosphate clusters and nickel complex fragments.

引用

页码：275 / 283

页数：9

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