Sulfur dioxide gas detection by reversible η1-SO2-Pt bond formation as a novel application for periphery functionalised metallo-dendrimers

被引：76
作者：
Albrecht, M
Gossage, RA
Spek, AL
van Koten, G
机构：
[1] Univ Utrecht, Debye Res Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands
[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 09期
关键词：
D O I：
10.1039/a708630j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Multimetallics such as dendrimer 3 which are functionalised at their periphery with platinum(II) metal centres reversibly absorb SO2 to yield macromolecules with significantly enhanced solubility characteristics and drastic colour changes; properties which make these compounds highly active sensors for milligram quantities of toxic SO2 gas.
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收藏
页码：1003 / 1004
页数：2
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