An easy conversion of the Baylis-Hillman adducts into tert-butyldimethylsilyl ethers with tert-butyldimethylsilyl chloride and Li2S

被引：4

作者：

Mamaghani, M ^{[1
]}

Badrian, A ^{[1
]}

机构：

[1] Guilan Univ, Fac Sci, Dept Chem, Rasht, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2004年 / 179卷 / 12期

关键词：

Baylis-Hillman adducts; tert-butyldimethylsilyl ethers; TBDMSCI; protecting group;

D O I：

10.1080/10426500490485291

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydroxy group of the Baylis-Hillman adducts is protected with the t-butyldimethylsilyl (TBDMS) group using the reaction of adducts 1a-h with tert-butyldimethylsilyl chloride (TBDMSCl) in the presence of lithium sulfide under nearly acidic reaction conditions.

引用

页码：2429 / 2435

页数：7

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