Facile protection of carbonyl compounds as oxathiolanes and transoxathioacetalization of oxyacetals promoted by iron(III) trifluoroacetate or trifluoromethanesulfonate as chemoselective and recyclable catalysts

被引:15
|
作者
Adibi, Hadi [1 ]
Jafari, Hadi
机构
[1] Kermanshah Univ Med Sci, Dept Med Chem, Kermanshah 6714967346, Iran
[2] Razi Univ, Dept Chem, Fac Sci, Kermanshah 67149, Iran
[3] Islamic Azad Univ, Dept Chem, Sci & Res Branch, Tehran 14515775, Iran
关键词
iron trifluoroacetate; trifluoromethanesulfonate; oxathiolanes; carbonyl compounds; protection;
D O I
10.1016/j.jfluchem.2007.04.002
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Oxathioacetalization of carbonyl compounds and transoxathioacetalization of O,O-acetals/ketals are reported under nearly neutral conditions promoted by iron(III) trifluoroacetate [Fe(CF3CO2)(3)] or trifluoromethanesulfonate [Fe(CF3SO3)(3)] as recyclable and highly efficient Lewis acid catalysts. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:679 / 682
页数:4
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