Facile protection of carbonyl compounds as oxathiolanes and transoxathioacetalization of oxyacetals promoted by iron(III) trifluoroacetate or trifluoromethanesulfonate as chemoselective and recyclable catalysts
被引:15
|
作者:
Adibi, Hadi
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机构:
Kermanshah Univ Med Sci, Dept Med Chem, Kermanshah 6714967346, IranKermanshah Univ Med Sci, Dept Med Chem, Kermanshah 6714967346, Iran
Adibi, Hadi
[1
]
Jafari, Hadi
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h-index: 0
机构:Kermanshah Univ Med Sci, Dept Med Chem, Kermanshah 6714967346, Iran
Jafari, Hadi
机构:
[1] Kermanshah Univ Med Sci, Dept Med Chem, Kermanshah 6714967346, Iran
[2] Razi Univ, Dept Chem, Fac Sci, Kermanshah 67149, Iran
[3] Islamic Azad Univ, Dept Chem, Sci & Res Branch, Tehran 14515775, Iran
iron trifluoroacetate;
trifluoromethanesulfonate;
oxathiolanes;
carbonyl compounds;
protection;
D O I:
10.1016/j.jfluchem.2007.04.002
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Oxathioacetalization of carbonyl compounds and transoxathioacetalization of O,O-acetals/ketals are reported under nearly neutral conditions promoted by iron(III) trifluoroacetate [Fe(CF3CO2)(3)] or trifluoromethanesulfonate [Fe(CF3SO3)(3)] as recyclable and highly efficient Lewis acid catalysts. (c) 2007 Elsevier B.V. All rights reserved.