Tuning the mechanical properties of SWNT/Nylon 6,10 composites with flexible spacers at the interface

被引:100
作者
Moniruzzaman, Mohammad
Chattopadhyay, Jayanta
Billups, W. Edward
Winey, Karen I.
机构
[1] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[2] Rice Univ, Dept Chem, Houston, TX 77005 USA
关键词
D O I
10.1021/nl062868e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have prepared nylon 6,10 nanocomposites using functionalized single wall carbon nanotubes and our interfacial in situ polycondensation method. The specific functional groups -(CH2)(n)COCl [n = 4 and 9] on the sidewalls of SWNT were designed to covalently link nanotubes to the nylon matrix via alkyl segments. The composites with functionalized SWNT show significant improvements in tensile modulus, strength, and toughness relative to nylon and nylon modified with nonfunctionalized SWNT. The alkyl linkages at the SWNT/nylon 6,10 interface contribute significantly to improving the toughness of the composites.
引用
收藏
页码:1178 / 1185
页数:8
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