Assembly of Two Metal-Organic Frameworks with Intrinsic Chiral Topology from Achiral Materials

被引：76

作者：

Jing, Xuemin ^{[1
]}

Zhang, Lirong ^{[1
]}

Ma, Tianliang ^{[1
]}

Li, Guanghua ^{[1
]}

Yu, Yang ^{[1
]}

Huo, Qisheng ^{[1
]}

Eddaoudi, Mohamed ^{[2
]}

Liu, Yunling ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

[2] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 02期

关键词：

ZEOLITIC IMIDAZOLATE FRAMEWORKS; COORDINATION POLYMERS; HYDROGEN; NETS; MOLECULES; CATALYSIS; SOLIDS; DESIGN; CHAINS; ACID;

D O I：

10.1021/cg9015096

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The assembly of Cu(CH3COO)(2)center dot H2O and pyridine-4,5-imidazoledicarboxylic acid (H(3)PylmDC) tinder solvothermal conditions in the presence of different organic templates yielded two three-dimensional chiral frameworks, vertical bar C3H10N2)(C3H7NO)(0.5)-(H2O)(2)vertical bar[(CuC10H5O4N3)-C-II] (1) and vertical bar(C4H9NO)(0.5)(H2O)(8)vertical bar[(Cu2CuI)-Cu-II(C10H5O4N3)(2)(C10H6O4N3)] (2). Both of the compounds crystallized in the cubic, P4(3)32 space group and possessed open helical channels in the frameworks. To the best of our knowledge, compounds 1 and 2 present the first synthesized MOFs with a bmn and lcy-a net. Further characterization of the two compounds has been performed, including X-ray powder diffraction, inductively coupled plasma analysis, CHN, IR spectra, fluorescence spectra, X-ray photoelectron spectroscopy spectrum and thermogravimetric-differential thermal analysis.

引用

页码：492 / 494

页数：3

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