Pentacene based Onsager crosses

被引:6
作者
Geyer, F. L. [1 ]
Schmid, S. [1 ]
Brosius, V. [1 ]
Bojanowski, N. M. [1 ]
Bollmann, G. [1 ]
Broedner, K. [1 ]
Bunz, U. H. F. [1 ,2 ]
机构
[1] Heidelberg Univ, Organ Chem Inst, Neuenheimer Feld 270, D-69120 Heidelberg, Germany
[2] Heidelberg Univ, CAM, Neuenheimer Feld 225, D-69120 Heidelberg, Germany
关键词
N-HETEROACENES; PERYLENE DIIMIDE;
D O I
10.1039/c6cc01029f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A dearomatization/aromatization strategy accesses the tetrahedral (crosslike) pentacene tetramer (tetrakis(4-((6,13-bis(TIPS-ethynyl)-pentacen-2-yl) ethynyl) phenyl) silane). This molecular caltrop and one of its derivatives form amorphous thin films, demonstrating the impact of the 3D-tetramerization on the bulk morphology of the otherwise crystalline TIPS-pentacene.
引用
收藏
页码:5702 / 5705
页数:4
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