Shear Nanostructuring of Monoglyceride Organogels

被引:192
作者
Da Pieve, Sara [1 ]
Calligaris, Sonia [1 ]
Co, Edmund [2 ]
Nicoli, Maria C. [1 ]
Marangoni, Alejandro G. [2 ]
机构
[1] Univ Udine, Dept Food Sci, I-33100 Udine, Italy
[2] Univ Guelph, Dept Food Sci, Ontario Agr Coll, Guelph, ON N1G 2W1, Canada
关键词
Saturated monoglycerides; Organogel; Shear; Self-assembly structures; ASSEMBLED FIBRILLAR NETWORKS; EDIBLE OILS; FATTY-ACIDS; 12-HYDROXYSTEARIC ACID; HYDROPHOBIC SOLUTIONS; MECHANICAL-PROPERTIES; BETA-SITOSTEROL; GAMMA-ORYZANOL; MATRIX;
D O I
10.1007/s11483-010-9162-3
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
The aim of the present research was to study the effect of shear on the crystallization behavior of monoglyceride organogels. To this end, organogels were prepared by mixing cod liver oil and saturated monoglycerides at 80A degrees C and then crystallizing them at 20A degrees C under shear rates ranging from 0 to 2,000 s(-1). The organogels were characterized using polarized light microscopy, Cryo-SEM, and X-ray diffraction. The rheological properties and the oil binding capacity of the different systems were also evaluated. Results obtained in this study showed that the introduction of shear during organogel formation greatly affects structure at the nano, micro, and macro levels. Solidification of the organogel under static conditions led to the formation of a strong gel network, with a high oil binding capacity. On the contrary, shear processing during crystallization led to the formation of a weak gel network with a low oil binding capacity.
引用
收藏
页码:211 / 217
页数:7
相关论文
共 30 条
[1]  
Adballah A. J., 2000, ADV MATER, V12, P1237
[2]   Free fatty acids and pathogenesis of type 2 diabetes mellitus [J].
Bergman, RN ;
Ader, M .
TRENDS IN ENDOCRINOLOGY AND METABOLISM, 2000, 11 (09) :351-356
[3]   Non-TAG structuring of edible oils and emulsions [J].
Bot, Arjen ;
Veldhuizen, Yvonne S. J. ;
den Adel, Ruud ;
Roijers, Eli C. .
FOOD HYDROCOLLOIDS, 2009, 23 (04) :1184-1189
[4]   Fibrils of γ-Oryzanol plus β-Sitosterol in Edible Oil Organogels [J].
Bot, Arjen ;
den Adel, Ruud ;
Roijers, Eli C. .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2008, 85 (12) :1127-1134
[5]   Structuring of edible oils by mixtures of γ-oryzanol with β-sitosterol or related phytosterols [J].
Bot, Arjen ;
Agterof, Wim G. M. .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2006, 83 (06) :513-521
[6]   Aging and Metastability of Monoglycerides in Hydrophobic Solutions [J].
Chen, C. H. ;
Terentjev, E. M. .
LANGMUIR, 2009, 25 (12) :6717-6724
[7]   Phase behavior of C18 monoglyceride in hydrophobic solutions [J].
Chen, C. H. ;
Van Damme, I. ;
Terentjev, E. M. .
SOFT MATTER, 2009, 5 (02) :432-439
[8]  
CLARK AH, 1987, ADV POLYM SCI, V83, P57
[9]   Development of a rheological method to characterize palm oil crystallizing under shear [J].
De Graef, Veerle ;
Goderis, Bart ;
Van Puyvelde, Peter ;
Foubert, Imogen ;
Dewettinck, Koen .
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2008, 110 (06) :521-529
[10]   Effects of crystalline microstructure on oil migration in a semisolid fat matrix [J].
Dibildox-Alvarado, E ;
Rodrigues, JN ;
Gioielli, LA ;
Toro-Vazquez, JF ;
Marangoni, AG .
CRYSTAL GROWTH & DESIGN, 2004, 4 (04) :731-736