IrPdRu/C as H2 Oxidation Catalysts for Alkaline Fuel Cells

被引:134
|
作者
Wang, Hongsen [1 ]
Abruna, Hector D. [1 ]
机构
[1] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA
关键词
ANION-EXCHANGE MEMBRANES; ROTATING-DISK ELECTRODE; HYDROGEN OXIDATION; OXYGEN REDUCTION; ELECTROCATALYSTS; EVOLUTION; RU; KINETICS; ACID;
D O I
10.1021/jacs.7b02434
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
H-2 oxidation kinetics on Pt in alkaline media are very sluggish, being over 100 times slower than in acidic media, and thus, new and more active H-2 oxidation electrocatalysts must be developed in order to enable alkaline exchange membrane fuel cells (AEMFCs). In this Communication, we present a new type of catalysts carbon-supported IrPdRu nanoparticles as H-2 oxidation catalysts in alkaline media. These catalysts exhibit higher activity than Pt/C and Ir/C catalysts and are also quite stable. In particular, Ir3Ru7/C and Ir3Pd1Ru6/C catalysts are significantly more active and less expensive than Pt/C and Ir/C, and are thus promising new anode catalysts for alkaline fuel cell applications.
引用
收藏
页码:6807 / 6810
页数:4
相关论文
共 50 条
  • [31] Kinetics of CO and H2 oxidation over CuO-CeO2 and CuO catalysts
    Avgouropoulos, George
    Ioannides, Theophilos
    CHEMICAL ENGINEERING JOURNAL, 2011, 176 : 14 - 21
  • [32] Ethanol electro-oxidation on Pt/C and PtSn/C catalysts in alkaline and acid solutions
    Jiang, L.
    Hsu, A.
    Chu, D.
    Chen, R.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (01) : 365 - 372
  • [33] Platinum group metal-free NiMo hydrogen oxidation catalysts: high performance and durability in alkaline exchange membrane fuel cells
    Kabir, Sadia
    Lemire, Kenneth
    Artyushkova, Kateryna
    Roy, Aaron
    Odgaard, Madeleine
    Schlueter, Debbie
    Oshchepkov, Alexandr
    Bonnefont, Antoine
    Savinova, Elena
    Sabarirajan, Dinesh C.
    Mandal, Pratiti
    Crumlin, Ethan J.
    Zenyuk, Iryna V.
    Atanassov, Plamen
    Serov, Alexey
    JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (46) : 24433 - 24443
  • [34] Highly active and durable Pd-Cu catalysts for oxygen reduction in alkaline exchange membrane fuel cells
    Peng, Xiong
    Omasta, Travis J.
    Roller, Justin M.
    Mustain, William E.
    FRONTIERS IN ENERGY, 2017, 11 (03) : 299 - 309
  • [35] Nonplatinum cathodic catalysts for fuel cells with alkaline electrolyte (Review)
    M. R. Tarasevich
    E. S. Davydova
    Russian Journal of Electrochemistry, 2016, 52 : 193 - 219
  • [36] Hydrogen Oxidation and Evolution Reaction on Platinum in Alkaline Electrolyte: Fixed Reference vs Overpotential and the Effect of H2 Concentration
    Heinritz, Adrian
    Binninger, Tobias
    Herranz, Juan
    Rodriguez, Paramaconi
    Schmidt, Thomas J.
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2024, 171 (11)
  • [37] Nonplatinum cathodic catalysts for fuel cells with alkaline electrolyte (Review)
    Tarasevich, M. R.
    Davydova, E. S.
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2016, 52 (03) : 193 - 219
  • [38] Alkaline polymer electrolyte fuel cells completely free from noble metal catalysts
    Lu, Shanfu
    Pan, Jing
    Huang, Aibin
    Zhuang, Lin
    Lu, Juntao
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2008, 105 (52) : 20611 - 20614
  • [39] Effect of the Nanosized TiO2 Particles in Pd/C Catalysts as Cathode Materials in Direct Methanol Fuel Cells
    Choi, Mahnsoo
    Han, Choonsoo
    Kim, In-Tae
    Lee, Ji-Jung
    Lee, Hong-Ki
    Shim, Joongpyo
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2011, 11 (07) : 6420 - 6424
  • [40] Palladium-Ceria Catalysts with Enhanced Alkaline Hydrogen Oxidation Activity for Anion Exchange Membrane Fuel Cells
    Bellini, Marco
    Pagliaro, Maria V.
    Lenarda, Anna
    Fornasiero, Paolo
    Marelli, Marcello
    Evangelisti, Claudio
    Innocenti, Massimo
    Jia, Qingying
    Mukerjee, Sanjeev
    Jankovic, Jasna
    Wang, Lianqin
    Varcoe, John R.
    Krishnamurthy, Chethana B.
    Grinberg, Ilya
    Davydova, Elena
    Dekel, Dario R.
    Miller, Hamish A.
    Vizza, Francesco
    ACS APPLIED ENERGY MATERIALS, 2019, 2 (07) : 4999 - 5008