Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand

被引：23

作者：

Kawakami, Ryosuke ^{[1
,2
]}

Kuriyama, Shogo ^{[1
,2
]}

Tanaka, Hiromasa ^{[3
]}

Arashiba, Kazuya ^{[1
,2
]}

Konomi, Asuka ^{[4
]}

Nakajima, Kazunari ^{[5
]}

Yoshizawa, Kazunari ^{[4
]}

Nishibayashi, Yoshiaki ^{[1
,2
]}

机构：

[1] Univ Tokyo, Dept Syst Innovat, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

[2] Univ Tokyo, Sch Engn, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

[3] Daido Univ, Sch Liberal Arts & Sci, Minami Ku, Nagoya, Aichi 4578530, Japan

[4] Kyushu Univ, Inst Mat Chem & Engn, Nishi Ku, Fukuoka, Fukuoka 8190395, Japan

[5] Univ Tokyo, Sch Engn, Frontier Res Ctr Energy & Resources, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 99期

关键词：

N-2-TO-NH3; CONVERSION; MOLECULAR DINITROGEN; SILYLATION; MOLYBDENUM; NITROGEN; AMMONIA; N-2; SILYLAMINE; REACTIVITY; TURNOVER;

D O I：

10.1039/c9cc06896a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions. This is the first successful example of rhodium-catalysed dinitrogen reduction undermild reaction conditions.

引用

页码：14886 / 14889

页数：4

共 54 条

[31] PREPARATION AND PROPERTIES OF MOLYBDENUM AND TUNGSTEN DINITROGEN COMPLEXES .25. CATALYTIC CONVERSION OF MOLECULAR NITROGEN INTO SILYLAMINES USING MOLYBDENUM AND TUNGSTEN DINITROGEN COMPLEXES [J].

KOMORI, K ;

OSHITA, H ;

MIZOBE, Y ;

HIDAI, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (05) :1939-1940

[32] Catalytic Transformations of Molecular Dinitrogen by Iron and Cobalt-Dinitrogen Complexes as Catalysts [J].

Kuriyama, Shogo ;

Nishibayashi, Yoshiaki .

NITROGEN FIXATION, 2017, 60 :215-234

[33] Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands [J].

Kuriyama, Shogo ;

Arashiba, Kazuya ;

Tanaka, Hiromasa ;

Matsuo, Yuki ;

Nakajima, Kazunari ;

Yoshizawa, Kazunari ;

Nishibayashi, Yoshiaki .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (46) :14289-14293

[34] Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand [J].

Kuriyama, Shogo ;

Arashiba, Kazuya ;

Nakajima, Kazunari ;

Matsuo, Yuki ;

Tanaka, Hiromasa ;

Ishii, Kazuyuki ;

Yoshizawa, Kazunari ;

Nishibayashi, Yoshiaki .

NATURE COMMUNICATIONS, 2016, 7

[35] Catalytic Dinitrogen Reduction at the Molybdenum Center Promoted by a Bulky Tetradentate Phosphine Ligand [J].

Liao, Qian ;

Saffon-Merceron, Nathalie ;

Mezailles, Nicolas .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (51) :14206-14210

[36]

Lu C.C., 2019, Transition Metal-Dinitrogen Complexes: Preparation and Reactivity, P337

[37] Synthesis and Application of Pyrrole-Based PNP-Ir Complexes to Catalytic Transfer Dehydrogenation of Cyclooctane [J].

Nakayama, Shin ;

Morisako, Shogo ;

Yamashita, Makoto .

ORGANOMETALLICS, 2018, 37 (08) :1304-1313

[38] Development of catalytic nitrogen fixation using transition metal-dinitrogen complexes under mild reaction conditions [J].

Nishibayashi, Yoshiaki .

DALTON TRANSACTIONS, 2018, 47 (33) :11290-11297

[39] Synthesis and Characterization of Bioinspired [Mo2Fe2]-Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N2 [J].

Ohki, Yasuhiro ;

Araki, Yuna ;

Tada, Mizuki ;

Sakai, Yoichi .

CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (53) :13240-13248

[40] Fe-Catalyzed Conversion of N2 to N(SiMe3)3 via an Fe-Hydrazido Resting State [J].

Piascik, Adam D. ;

Li, Ruohao ;

Wilkinson, Harry J. ;

Green, Jennifer C. ;

Ashley, Andrew E. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (34) :10691-10694

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