Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand

被引：23

作者：

Kawakami, Ryosuke ^{[1
,2
]}

Kuriyama, Shogo ^{[1
,2
]}

Tanaka, Hiromasa ^{[3
]}

Arashiba, Kazuya ^{[1
,2
]}

Konomi, Asuka ^{[4
]}

Nakajima, Kazunari ^{[5
]}

Yoshizawa, Kazunari ^{[4
]}

Nishibayashi, Yoshiaki ^{[1
,2
]}

机构：

[1] Univ Tokyo, Dept Syst Innovat, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

[2] Univ Tokyo, Sch Engn, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

[3] Daido Univ, Sch Liberal Arts & Sci, Minami Ku, Nagoya, Aichi 4578530, Japan

[4] Kyushu Univ, Inst Mat Chem & Engn, Nishi Ku, Fukuoka, Fukuoka 8190395, Japan

[5] Univ Tokyo, Sch Engn, Frontier Res Ctr Energy & Resources, Bunkyo Ku, Hongo, Tokyo 1138656, Japan

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 99期

关键词：

N-2-TO-NH3; CONVERSION; MOLECULAR DINITROGEN; SILYLATION; MOLYBDENUM; NITROGEN; AMMONIA; N-2; SILYLAMINE; REACTIVITY; TURNOVER;

D O I：

10.1039/c9cc06896a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions. This is the first successful example of rhodium-catalysed dinitrogen reduction undermild reaction conditions.

引用

页码：14886 / 14889

页数：4

共 54 条

[1] Catalytic conversion of nitrogen to ammonia by an iron model complex [J].

Anderson, John S. ;

Rittle, Jonathan ;

Peters, Jonas C. .

NATURE, 2013, 501 (7465) :84-+

[2]

[Anonymous], 2019, TRANSITION METAL DIN

[3] [Fe4] and [Fe6] Hydride Clusters Supported by Phosphines: Synthesis, Characterization, and Application in N2 Reduction [J].

Araake, Ryoichi ;

Sakadani, Kazuki ;

Tada, Mizuki ;

Sakai, Yoichi ;

Ohki, Yasuhiro .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (15) :5596-5606

[4] Catalytic Nitrogen Fixation via Direct Cleavage of Nitrogen-Nitrogen Triple Bond of Molecular Dinitrogen under Ambient Reaction Conditions [J].

Arashiba, Kazuya ;

Eizawa, Aya ;

Tanaka, Hiromasa ;

Nakajima, Kazunari ;

Yoshizawa, Kazunari ;

Nishibayashi, Yoshiaki .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2017, 90 (10) :1111-1118

[5] Catalytic Reduction of Dinitrogen to Ammonia by Use of Molybdenum-Nitride Complexes Bearing a Tridentate Triphosphine as Catalysts [J].

Arashiba, Kazuya ;

Kinoshita, Eriko ;

Kuriyama, Shogo ;

Eizawa, Aya ;

Nakajima, Kazunari ;

Tanaka, Hiromasa ;

Yoshizawa, Kazunari ;

Nishibayashi, Yoshiaki .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (17) :5666-5669

[6] A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia [J].

Arashiba, Kazuya ;

Miyake, Yoshihiro ;

Nishibayashi, Yoshiaki .

NATURE CHEMISTRY, 2011, 3 (02) :120-125

[7] A Practical Synthesis of Ammonia from Nitrogen Gas, Samarium Diiodide and Water Catalyzed by a Molybdenum-PCP Pincer Complex [J].

Ashida, Yuya ;

Kondo, Shoichi ;

Arashiba, Kazuya ;

Kikuchi, Takamasa ;

Nakajima, Kazunari ;

Kakimoto, Seizo ;

Nishibayashi, Yoshiaki .

SYNTHESIS-STUTTGART, 2019, 51 (20) :3792-3795

[8] Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands [J].

Ashida, Yuya ;

Arashiba, Kazuya ;

Tanaka, Hiromasa ;

Egi, Akihito ;

Nakajima, Kazunari ;

Yoshizawa, Kazunari ;

Nishibayashi, Yoshiaki .

INORGANIC CHEMISTRY, 2019, 58 (14) :8927-8932

[9] Molybdenum-catalysed ammonia production with samarium diiodide and alcohols or water [J].

Ashida, Yuya ;

Arashiba, Kazuya ;

Nakajima, Kazunari ;

Nishibayashi, Yoshiaki .

NATURE, 2019, 568 (7753) :536-+

[10] N2-to-NH3 Conversion by a triphos-Iron Catalyst and Enhanced Turnover under Photolysis [J].

Buscagan, Trixia M. ;

Oyala, Paul H. ;

Peters, Jonas C. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (24) :6921-6926

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