Modelling the photochemistry of imazethapyr in rice paddy water

In this work the photochemistry of imazethapyr, an imidazolinone herbicide used in rice crops, was modelled in rice paddy water. The photochemical half-life time of the herbicide was assessed by means of the APEX software (Aqueous Photochemistry of Environmentally occurring Xenobiotics) taking into account the direct photolysis, the reactions with hydroxyl radicals (HO center dot) and, in some cases, the reactions with the excited triplet states of chromophoric dissolved organic matter ((CDOM)-C-3*). We found that direct photolysis and HO center dot reaction can account for a half-life time ranging between 8 and 11 days in May, which is in quite good agreement with the half-life times measured in the field and reported in the literature. These findings suggest that direct photolysis and reaction with HO center dot are important degradation pathways for imazethapyr in paddy water. Dissolved organic matter (DOM) has been reported in the literature to decrease the imazethapyr photodegradation rate. Our model computations confirm this finding but, upon comparison of model predictions with experimental data from the literature, we provide evidence of a non-negligible role of DOM-photosensitised processes in imazethapyr degradation, particularly in DOM-rich waters. We also assess an upper limit (10(8) L mol(-1) s(-1)) for the second-order rate constant of the reaction between imazethapyr and 3CDOM*. Furthermore, on the basis of literature-reported photodegradation pathways and by using both APEX and the US-EPA ECOSAR V2.0 software, we assess that the direct photolysis by-products of imazethapyr could pose a potential ecotoxicological threat to aquatic systems. (C) 2018 Elsevier B.V. All rights reserved.