Construction of Covalent Organic Frameworks Bearing Three Different Kinds of Pores through the Heterostructural Mixed Linker Strategy

被引：267
作者：
Pang, Zhong-Fu [1 ]
Xu, Shun-Qi [1 ]
Zhou, Tian-You [1 ]
Liang, Rong-Ran [1 ]
Zhan, Tian-Guang [1 ]
Zhao, Xin [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet & Self Assembly Chem Organ Funct, 345 Lingling Rd, Shanghai 200032, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2016年 / 138卷 / 14期
基金：
中国国家自然科学基金;
关键词：
THIN-FILMS; ENERGY-STORAGE; CRYSTALLINE; CATALYSIS; CLUSTERS; AREA;
D O I：
10.1021/jacs.6b01244
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
It is very important to create novel topologies and improve structural complexity for covalent organic frameworks (COFs) that might lead to unprecedented properties and applications. Despite the progress achieved over the past decade, the structural diversity and complexity of COFs are quite limited. In this Communication, we report the construction of COFs bearing three different kinds of pores through the heterostructural mixed linker strategy involving the condensation of a D-2h-symmetric tetraamine and two C-2-symmetric dialdehydes of different lengths. The complicated structures of the triple-pore COFs have been confirmed by powder X-ray diffraction and pore size distribution analyses.
引用
收藏
页码：4710 / 4713
页数：4
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