Novel nonperipheral octa-3-hydroxypropylthio substituted metallo-phthalocyanines: synthesis, characterization, and investigation of their electrochemical, photochemical and computational properties

被引：2

作者：

Kabay, Nilgun ^{[1
]}

Baygu, Yasemin ^{[2
]}

Metin, A. K. ^{[3
]}

Kara, Izzet ^{[4
]}

Kaya, Esra Nur ^{[5
]}

Durmus, Mahmut ^{[5
]}

GoK, Yasar ^{[6
]}

机构：

[1] Pamukkale Univ, Dept Biomed Engn, Denizli, Turkey

[2] Pamukkale Univ, Tavas Vocat Sch Higher Educ, Denizli, Turkey

[3] Pamukkale Univ, Dept Chem, Denizli, Turkey

[4] Pamukkale Univ, Dept Phys Educ, Denizli, Turkey

[5] Gebze Tech Univ, Dept Chem, Kocaeli, Turkey

[6] Usak Univ, Dept Chem Engn, Usak, Turkey

来源：

TURKISH JOURNAL OF CHEMISTRY | 2021年 / 45卷 / 01期

关键词：

Metallo-phthalocyanines; cyclic voltammetry; computational chemistry; photodynamic therapy; photochemical properties; MAIN ABSORPTION; HYDROGENATION; FLUORESCENCE; GROUP-11; ZN;

D O I：

10.3906/kim-2008-48

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The current study describes the synthesis, electrochemical, computational, and photochemical properties of octa (3-hydroxypropylthio) substituted cobalt (II) (4), copper (II) (5), nickel (II) (6) and zinc(II) (7) phthalocyanine derivatives. These novel compounds were characterized by elemental analysis, H-1, C-13 NMR, FT-IR, UV-Vis, and MS. The redox behaviors of these metallophthalocyanines were investigated by the cyclic voltammetric method. The optimized molecular structure and gauge-including atomic orbital (GIAO) H-1 and C-13 NMR chemical shift values of these phthalocyanines in the ground state had been calculated by using B3LYP/6-31G(d,p) basis set. The outcomes of the optimized molecular structure were given and compared with the experimental NMR values. The photochemical properties including photodegradation and singlet oxygen generation of zinc(II) phthalocyanine were studied in DMSO solution for the determination of its photosensitizer behaviors.

引用

页码：143 / +

页数：27

共 49 条

[1] A highly water-soluble zinc(II) phthalocyanines as potential for PDT studies: Synthesis and characterization [J].