Syntheses and crystal structures of cyano-bridged cluster-metal layered coordination polymers [Cu(dien)]3[W4Te4(CN)12]•9H2O and [Ni(en)(NH3)]3[W4Se4(CN)12]•7.5H2O

被引：8
作者：
Kalinina, IV
Virovets, AV
Dolgushin, FM
Antipin, MY
Llusar, R
Fedin, VP
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolayev Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow, Russia
[3] Univ Jaume 1, Dept Expt Sci, Castellon de La Plana, Spain
来源：
INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 11期
基金：
俄罗斯基础研究基金会;
关键词：
coordination polymers; tungsten; clusters; cyanides; copper; nickel;
D O I：
10.1016/j.ica.2004.03.036
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new tetrahedral tungsten cyanide cluster compounds, [Cu(dien)](3)[W4Te4(CN)(12)](.)9H(2)O (1) (dien = diethylenetriamine) and [Ni(en)(NH3)](3)[W4Se4(CN)(12)](.)7.5H(2)O (2) (en = ethylenediamine), were synthesized by treating aqueous solutions of the saltlike cluster compound K-6[W4Te4(CN)(12)](.)5H(2)O/K-6[W4Se4(CN)(12)](.)6H(2)O With copper(II)/nickel(II) chloride in aqueous ammonia containing dien/en. The cyano-bridged layered coordination polymeric compounds were characterized by single-crystal X-ray diffraction analysis: monoclinic, space group P2(1) for 1; trigonal, space group R (3) over bar for 2. Structures of 1 and 2 consist of infinite neutral layers of cluster components {W4Te4(CN)(12)}/{W4Se4(CN)(12)} connected, one another by {Cu(dien)} or {Ni(en)(NH3)} fragments, respectively. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：3390 / 3396
页数：7
相关论文
共 26 条
[1]  
[Anonymous], 1998, SMART V5 051 SAINT V
[2]   New polymeric structure of rhenium octahedral chalcocyanide complex:: Ln3+-derived network with one-dimensional channels [J].
Artemkina, SB ;
Naumov, NG ;
Virovets, AV ;
Gromilov, SA ;
Fenske, D ;
Fedorov, VE .
INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (08) :423-426
[3]   Cyano-bridged Re6Q8 (Q = S, Se) Cluster-Cobalt(II) framework materials:: Versatile solid chemical sensors [J].
Beauvais, LG ;
Shores, MP ;
Long, JR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (12) :2763-2772
[4]   Expanded Prussian blue analogues incorporating [Re6Se8(CN)6]3-/4- clusters:: Adjusting porosity via charge balance [J].
Bennett, MV ;
Beauvais, LG ;
Shores, MP ;
Long, JR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) :8022-8032
[5]   Expansion of the porous solid Na2Zn3[Fe(CN)6]2•9H2O:: Enhanced ion-exchange capacity in Na2Zn3[Re6Se8(CN)6]2•24H2O [J].
Bennett, MV ;
Shores, MP ;
Beauvais, LG ;
Long, JR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (28) :6664-6668
[6]  
Dunbar KR, 1997, PROG INORG CHEM, V45, P283
[7]   First complexes with cuboidal-type M4Te4 (M=Mo, W) cluster cores:: synthesis and structure of K7[Mo4(μ3-Te)4(CN)12]•11H2O and K6[W4(μ3-Te)4(CN)12]•5H2O [J].
Fedin, VP ;
Kalinina, IV ;
Virovets, AV ;
Podberezskaya, NV ;
Sykes, AG .
CHEMICAL COMMUNICATIONS, 1998, (02) :237-238
[8]  
Fedin VP, 2000, EUR J INORG CHEM, P2341
[9]   Synthesis, structure, and properties of molybdenum and tungsten cyano complexes with cuboidal M4(μ3-E)4 (M = Mo, W; E = S, Se, Te) cores [J].
Fedin, VP ;
Kalinina, IV ;
Samsonenko, DG ;
Mironov, YV ;
Sokolov, MN ;
Tkachev, SV ;
Virovets, AV ;
Podberezskaya, NV ;
Elsegood, MRJ ;
Clegg, W ;
Sykes, AG .
INORGANIC CHEMISTRY, 1999, 38 (09) :1956-1965
[10]   Syntheses and structures of layered compounds based on lanthanides(III) and cubane molybdenum and tungsten telluride cyano complexes [J].
Fedin, VP ;
Kalinina, IV ;
Virovets, AV ;
Fenske, D .
RUSSIAN CHEMICAL BULLETIN, 2003, 52 (01) :126-131
123