Solid-state polymer nanocomposite electrolyte of TiO2/PEO/NaClO4 for sodium ion batteries

被引：265

作者：

Ni'mah, Yatim Lailun ^{[1
]}

Cheng, Ming-Yao ^{[1
]}

Cheng, Ju Hsiang ^{[1
]}

Rick, John ^{[1
]}

Hwang, Bing-Joe ^{[1
,2
]}

机构：

[1] Natl Taiwan Univ Sci & Technol, Dept Chem Engn, Taipei 106, Taiwan

[2] Natl Synchrotron Radiat Res Ctr, Hsinchu 300, Taiwan

来源：

JOURNAL OF POWER SOURCES | 2015年 / 278卷

关键词：

Sodium ion battery; Polymer electrolyte; PEO; Conductivity; NaClO4; TiO2; POLY(ETHYLENE OXIDE); POLYETHYLENE OXIDE; CONDUCTIVITY; CHALLENGES; TRANSPORT;

D O I：

10.1016/j.jpowsour.2014.11.047

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A free-standing transparent film for sodium-ion conduction in PEO-based solid polymer electrolyte (additionally comprising NaClO4 and nano-sized TiO2) has been fabricated for use in Na-ion batteries by using a solution casting technique. The crystallinity of the solid polymer electrolyte and the interactions between PEO and the Na-ions is characterized by X-ray diffraction (XRD) and Fourier transformed infrared (FTIR) spectra, which reveals the degree of Na+ ion solvation by PEO oxygen atoms (EO:Na). The ionic conductivities of the films are investigated by impedance analysis from 1 MHz to 1 Hz within the temperature range 303-363 K. A solid polymer electrolyte with anatomic ratio EO:Na = 20 exhibits a maximum ionic conductivity of 1.35 x 10(-4) S cm(-1), which increases to 2.62 x 10(-4) S cm(-1) by the addition of TiO2 (3.4 nm, 5 wt%) at temperature 60 degrees C. The performance of a Na2/3CO2/3Mn1/3O2 half cell with a polymer electrolyte is compared to a similar cell with a liquid electrolyte. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：375 / 381

页数：7

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