Corrosion inhibition effect of sodium iodide for mild steel in 1 M hydrochloric acid: Gravimetrical and electrochemical studies

被引:14
作者
Ahmaeed, W. N. [1 ]
Abd, A. N. [1 ]
Khadom, A. A. [2 ]
机构
[1] Univ Ayala, Coll Sci, Dept Chem, Baquba City 32001, Diyala Governor, Iraq
[2] Univ Ayala, Coll Sci, Dept Chem Engn, Baquba City 32001, Diyala Governor, Iraq
来源
INTERNATIONAL JOURNAL OF CORROSION AND SCALE INHIBITION | 2019年 / 8卷 / 04期
关键词
corrosion; inorganic inhibitor; mild steel; acidic solution; LOW-CARBON STEEL; ADSORPTION; KINETICS;
D O I
10.17675/2305-6894-2019-8-4-17
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The corrosion inhibition behavior of mild steel in 1 M HCl was investigated in the absence and the presence of sodium iodide (NaI) as an inorganic corrosion inhibitor. The influence of temperature, time and inhibitor concentration was studied using weight loss technique and Tafel polarization technique. The results showed that NaI act as a powerful inhibitor and the inhibition efficiency increase with increase in inhibitor concentration, time and temperature. Maximum inhibition efficiency was 96.1% at a higher level of inhibitor concentration, time and temperature. The adsorption of NaI on mild steel surface was found to follow Langmuir adsorption isotherm. The values of the free energy of adsorption were between - 20 and - 40 kJ/mol that indicate the cooperative adsorption (physical and chemical adsorption). The activation energy of the corrosion process was evaluated using Arrhenius-type equation. Electrochemical studies confirmed the inhibition action of NaI. Corrosion current densities moved to lower value with the addition of NaI. Inhibition efficiency values were in a good agreement with weight loss results. The shift of corrosion potential by iodide anion was lower than 85 mV indicates that it inhibits the anodic reaction and the cathodic reaction, which confirm that sodium iodide act as a mixed - type inhibitor.
引用
收藏
页码:1097 / 1111
页数:15
相关论文
共 20 条
[1]   Adsorption and inhibitive properties of some new Mannich bases of Isatin derivatives on corrosion of mild steel in acidic media [J].
Ahamad, Ishtiaque ;
Prasad, Rajendra ;
Quraishi, M. A. .
CORROSION SCIENCE, 2010, 52 (04) :1472-1481
[2]   Ruthenium-ligand complex, an efficient inhibitor of steel corrosion in H3PO4 media [J].
Benabdellah, M. ;
Touzani, R. ;
Dafali, A. ;
Hammouti, B. ;
El Kadiri, S. .
MATERIALS LETTERS, 2007, 61 (4-5) :1197-1204
[3]   Caffeic acid as a green corrosion inhibitor for mild steel [J].
de Souza, F. S. ;
Spinelli, A. .
CORROSION SCIENCE, 2009, 51 (03) :642-649
[4]  
El Din AMS, 1997, DESALINATION, V114, P85
[5]   THE EFFECT OF TEMPERATURE ON THE POLARIZATION RESISTANCE .1. ACTIVATION CONTROL [J].
ELANADOULI, BE ;
ATEYA, BG ;
ELNIZAMY, FM .
CORROSION SCIENCE, 1986, 26 (06) :419-424
[6]   (S)-6-Phenyl-2,3,5,6-tetrahydroimidazo[2,1-b] thiazole hydrochloride as corrosion inhibitor of steel in acidic solution: Gravimetrical, electrochemical, surface morphology and theoretical simulation [J].
Fadhil, Ahmed A. ;
Khadom, Anees A. ;
Liu, Hongfang ;
Fu, Chaoyang ;
Wang, Junlei ;
Fadhil, Noor A. ;
Mahood, Hameed B. .
JOURNAL OF MOLECULAR LIQUIDS, 2019, 276 :503-518
[7]   A comprehensive study on crude methanolic extract of Artemisia pallens (Asteraceae) and its active component as effective corrosion inhibitors of mild steel in acid solution [J].
Garai, Subhadra ;
Garai, Saraswati ;
Jaisankar, Parasuraman ;
Singh, J. K. ;
Elango, Adirajan .
CORROSION SCIENCE, 2012, 60 :193-204
[8]  
Khadom Anees A., 2018, South African Journal of Chemical Engineering, V25, P13, DOI 10.1016/j.sajce.2017.11.002
[9]   Modeling of corrosion inhibition of copper-nickel alloy in hydrochloric acid by benzotriazole [J].
Khadom, A. A. ;
Yaro, A. S. .
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 85 (11) :2005-2012
[10]   Electrochemical, Activations and Adsorption Studies for the Corrosion Inhibition of Low Carbon Steel in Acidic Media [J].
Khadom, A. A. ;
Yaro, A. S. ;
AlTaie, A. S. ;
Kadum, A. A. H. .
PORTUGALIAE ELECTROCHIMICA ACTA, 2009, 27 (06) :699-712