Ruthenium polyoxometalate water splitting catalyst: very fast hole scavenging from photogenerated oxidants

被引：144
作者：
Orlandi, Michele [3 ]
Argazzi, Roberto [4 ]
Sartorel, Andrea [1 ,2 ]
Carraro, Mauro [1 ,2 ]
Scorrano, Gianfranco [1 ,2 ]
Bonchio, Marcella [1 ,2 ]
Scandola, Franco [3 ]
机构：
[1] Univ Padua, CNR, ITM, I-35131 Padua, Italy
[2] Univ Padua, Dept Chem Sci, I-35131 Padua, Italy
[3] Univ Ferrara, Dept Chem, Interuniv Res Ctr Chem Convers Solar Energy, I-44121 Ferrara, Italy
[4] CNR, ISOF, Sez Ferrara, I-44121 Ferrara, Italy
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 18期
关键词：
ELECTRON-TRANSFER; OXYGEN EVOLUTION; OXIDATION; COMPLEXES; EFFICIENT; FAMILY; DIMER;
D O I：
10.1039/b926823e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The tetraruthenium polyoxometalate water oxidation catalyst 1 performs very fast hole scavenging from photogenerated Ru(III) polypyridine complexes, both in homogeneous solution and at a sensitized nanocrystalline TiO2 surface.
引用
收藏
页码：3152 / 3154
页数：3
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