Supported Palladium Oxide Nanoparticles in SBA-15 as a Heterogeneous Catalyst for the Aerobic Oxidation of Alcohols

被引：9

作者：

Atashin, Hassan ^{[1
]}

Malakooti, Reihaneh ^{[1
]}

机构：

[1] Univ Birjand, Dept Chem, Nanochem Res Lab, Birjand, Iran

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2014年 / 61卷 / 09期

关键词：

SBA-15; Heterogeneous catalyst; Palladium oxide nanoparticles; Aerobic oxidation of alcohols; MESOPOROUS SILICA; SELECTIVE OXIDATION; MOLECULAR-OXYGEN; IMMOBILIZATION; CHANNELS;

D O I：

10.1002/jccs.201300609

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium nanoparticles were first synthesized through the thermal decomposition method and subsequently immobilized on orderedmesoporous silicamaterial, SBA-15, to afford PdO/SBA-15 catalyst. The synthesized catalyst was characterized by X-ray diffraction, nitrogen adsorption-desorption measurement, transmission electron microscopy, and inductively coupled plasma atomic emission spectrometry. The catalytic activity was tested for the aerobic oxidation of alcohols. Easy recovery, high yeilds and relatively short reaction times were observed for the mentioned catalyst.

引用

页码：1039 / 1044

页数：6

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