Progress in the synthesis of aldehydes from Pd-catalyzed Wacker-type reactions of terminal olefins

被引：18
作者：
Muzart, Jacques [1 ]
机构：
[1] Univ Reims, CNRS, UMR 7312, Inst Chim Mol Reims, BP 1039, F-51687 Reims 2, France
来源：
TETRAHEDRON | 2021年 / 87卷
关键词：
Palladium; Wacker reaction; Terminal olefins; Aldehydes; Oxidation; Anti-Markovnikov addition; ANTI-MARKOVNIKOV OXIDATION; MOLECULAR-OXYGEN; METHYL KETONES; AEROBIC OXIDATION; PALLADIUM(II)-CATALYZED OXIDATION; SELECTIVE OXIDATION; REGIOSELECTIVE OXIDATION; PALLADIUM COMPLEX; INTERNAL OLEFINS; ALKENES;
D O I：
10.1016/j.tet.2021.132024
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Wacker-type reactions of terminal alkenes mainly lead to methyl ketones rather than aldehydes. The selective formation of aldehydes usually requires alkenes containing a suitable coordinating fragment. A few procedures however provide fair to high aldehyde/methyl ketone ratios in the absence of a directing group. This review, which is focused on the formation of aldehydes, summarizes the methods reported since 2007 and, with personal comments, the mechanisms and intermediates proposed to rationalize the regioselectivity. (C) 2021 Elsevier Ltd. All rights reserved.
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页数：35
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