MIL-53(Fe): Introduction of a new catalyst for the synthesis of Pyrimido[4,5-d]pyrimidine derivatives under solvent-free conditions

被引：19

作者：

Abdollahi-Basir, Mohammad Hossein ^{[1
]}

Shirini, Farhad ^{[1
]}

Tajik, Hassan ^{[1
]}

Ghasemzadeh, Mohammad Ali ^{[2
]}

机构：

[1] Univ Guilan, Coll Sci, Dept Chem, Rasht 4133519141, Iran

[2] Islamic Azad Univ, Dept Chem, Qom Branch, Qom, Iran

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2019年 / 1197卷

关键词：

Pyrimido[4,5-d]pyrimidine; Metal-organic framework; MIL-53(Fe); Heterocyclic; Solvent-free; METAL-ORGANIC FRAMEWORKS; POT MULTICOMPONENT SYNTHESIS; EFFICIENT; ACTIVATION; PYRIMIDO; CORE;

D O I：

10.1016/j.molstruc.2019.07.065

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this study, the efficiency of MIL-53(Fe) metal-organic framework (MOF) the one-pot, three-component reaction of isothiocyanate, aromatic aldehydes and 6-aminouracil and/or N,N-dimethyl-6-aminouracil to form pyrimido[4,5-d]pyrimidine derivatives is investigated. Using this method all reactions are performed at 110 degrees C under solvent-free conditions with good to excellent product yields during acceptable reaction times. The other important merit of this method is simple recovery of MIL-53(Fe) through filtration which makes it reusable for further cycles without considerable decrease in its activity. The method is demonstrated to be a truly green process with sustainability and economics. (C) 2019 Elsevier B.V. All rights reserved.

引用

页码：318 / 325

页数：8

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