Comprehensive particle characterization of modern gasoline and diesel passenger cars at low ambient temperatures

Particle measurements were performed in the exhaust of five light-duty vehicles (Euro-3) at +23, -7, and -20 degreesC ambient temperatures. The characterization included measurements of particle number. active surface area. number size distribution, and mass size distribution. We investigated two port-injection spark-ignition (PISI) vehicles. a direct-injection spark-ignition (DISI) vehicle, a compressed ignition (CI) vehicle with diesel particle filter (DPF), and a CI vehicle without DPF. To minimize sampling effects, particles were directly sampled from the tailpipe with a novel porous tube diluter at controlled sampling parameters. The diluted exhaust was split into two branches to measure either all or only non-volatile particles. Effect of ambient temperature was investigated on particle emission for cold and warmed-up engine. For the gasoline vehicles and the CI vehicle with DPF. the main portion of particle emission was found in the first minutes of the driving cycle at cold engine start. The particle emission of the CI vehicle without DPF was hardly affected by cold engine start. For the PISI vehicles, particle number emissions were super-proportionally increased in the diameter size range from 0.1 to 0.3 mum during cold start at low ambient temperature. Based on the particle mass size distribution, the DPF removed smaller particles (dp<0.5 mum) more efficiently than larger particles (dp>0.5 mum). No significant effect of ambient temperature was observed when the engine was warmed up. Peak emission of volatile nanoparticles only took place at specific conditions and was poorly repeatable. Nucleation of particles was predominately observed during or after strong acceleration at high speed and during regeneration of the DPF. (C) 2004 Elsevier Ltd. All rights reserved.