Converting p-terphenyl into a novel organo-catalyst for LED-driven energy and electron transfer photoreactions in water

被引：15
作者：
Bertrams, Maria-Sophie [1 ]
Kerzig, Christoph [1 ]
机构：
[1] Johannes Gutenberg Univ Mainz, Dept Chem, Duesbergweg 10-14, D-55128 Mainz, Germany
来源：
CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 55期
关键词：
PHOTOREDOX CATALYSIS; CARBON-DIOXIDE; PHOTOCATALYSIS;
D O I：
10.1039/d1cc01947c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
p-Terphenyl is a potent photoredox catalyst under UV-irradiation. Aiming for more sustainable reaction conditions, we added two sulfonate groups to this key structure to achieve water solubility and incorporated an SO2-bridge thereby shifting the absorption spectrum towards the visible. The resulting photocatalyst shows unexpected triplet reactivity in several test reactions.
引用
收藏
页码：6752 / 6755
页数：4
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