Converting p-terphenyl into a novel organo-catalyst for LED-driven energy and electron transfer photoreactions in water

被引：15
作者：
Bertrams, Maria-Sophie [1 ]
Kerzig, Christoph [1 ]
机构：
[1] Johannes Gutenberg Univ Mainz, Dept Chem, Duesbergweg 10-14, D-55128 Mainz, Germany
来源：
CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 55期
关键词：
PHOTOREDOX CATALYSIS; CARBON-DIOXIDE; PHOTOCATALYSIS;
D O I：
10.1039/d1cc01947c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
p-Terphenyl is a potent photoredox catalyst under UV-irradiation. Aiming for more sustainable reaction conditions, we added two sulfonate groups to this key structure to achieve water solubility and incorporated an SO2-bridge thereby shifting the absorption spectrum towards the visible. The resulting photocatalyst shows unexpected triplet reactivity in several test reactions.
引用
收藏
页码：6752 / 6755
页数：4
相关论文
共 43 条
  • [1] Enantioselective photochemistry through Lewis acid-catalyzed triplet energy transfer
    Blum, Travis R.
    Miller, Zachary D.
    Bates, Desiree M.
    Guzei, Ilia A.
    Yoon, Tehshik P.
    [J]. SCIENCE, 2016, 354 (6318) : 1391 - 1395
  • [2] On the Sustainability of Photochemical Reactions
    Bochet, Christian G.
    [J]. CHIMIA, 2019, 73 (09) : 720 - 723
  • [3] PQS-enabled visible-light iridium photoredox catalysis in water at room temperature
    Bu, Mei-Jie
    Cai, Chun
    Gallou, Fabrice
    Lipshutz, Bruce H.
    [J]. GREEN CHEMISTRY, 2018, 20 (06) : 1233 - 1237
  • [4] Chemistry glows green with photoredox catalysis
    Crisenza, Giacomo E. M.
    Melchiorre, Paolo
    [J]. NATURE COMMUNICATIONS, 2020, 11 (01)
  • [5] Strongly Reducing, Visible-Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals
    Du, Ya
    Pearson, Ryan M.
    Lim, Chern-Hooi
    Sartor, Steven M.
    Ryan, Matthew D.
    Yang, Haishen
    Damrauer, Niels H.
    Miyake, Garret M.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (46) : 10962 - +
  • [6] Rational Design of Triplet Sensitizers for the Transfer of Excited State Photochemistry from UV to Visible
    Elliott, Luke D.
    Kayal, Surajit
    George, Michael W.
    Booker-Milburn, Kevin
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (35) : 14947 - 14956
  • [7] Modulation of Acridinium Organophotoredox Catalysts Guided by Photophysical Studies
    Fischer, Christian
    Kerzig, Christoph
    Zilate, Bouthayna
    Wenger, Oliver S.
    Sparr, Christof
    [J]. ACS CATALYSIS, 2020, 10 (01) : 210 - 215
  • [8] Rate and driving force for protonation of aryl radical anions in ethanol
    Funston, Alison M.
    Lymar, Sergei V.
    Saunders-Price, Barbara
    Czapski, Gidon
    Miller, John R.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (24) : 6895 - 6902
  • [9] A designed bi- functional sugar- based surfactant: micellar catalysis for C- X coupling reaction in water
    Ge, Xin
    Zhang, Shihui
    Chen, Xinzhi
    Liu, Xuemin
    Qian, Chao
    [J]. GREEN CHEMISTRY, 2019, 21 (10) : 2771 - 2776
  • [10] Photocatalytic activation of alkyl chlorides by assembly-promoted single electron transfer in microheterogeneous solutions
    Giedyk, Maciej
    Narobe, Rok
    Weiss, Sophia
    Touraud, Didier
    Kunz, Werner
    Koenig, Burkhard
    [J]. NATURE CATALYSIS, 2020, 3 (01) : 40 - 47
12345