TiO2 supported over porous silica photocatalysts for pesticide degradation using solar light: Part 2. Silica prepared using acrylic acid emulsion

被引:30
作者
Sharma, Mangalampalli V. Phanikrishna [1 ]
Kumari, Valluri Durga [1 ]
Subrahmanyam, Machiraju [1 ]
机构
[1] Indian Inst Chem Technol, Inorgan & Phys Chem Div, Hyderabad 500607, Andhra Pradesh, India
关键词
Porous silica material; TiO2; Isoproturon; Photocatalysis; Degradation; WATER; EFFICIENT; ROUTE; DYES; UV;
D O I
10.1016/j.jhazmat.2009.10.056
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
An acrylic acid emulsion mixture is used for synthesis of novel porous silica (E-Si) material. The photocatalytic activity of TiO2 under solar light irradiation for isoproturon (herbicide) degradation is drastically increased when dispersed over E-Si support using solid state dispersion (SSD) technique. The composite material is characterized by XRD, nitrogen adsorption-desorption isotherms, UV-vis DRS, SEM and TEM measurements. The photocatalytic activities of the composite catalysts are evaluated for different parameters. The 5 wt% TiO2/E-Si is found to be highly active for isoproturon degradation. (C) 2009 Published by Elsevier B.V.
引用
收藏
页码:1101 / 1105
页数:5
相关论文
共 20 条
  • [1] TEMPLATING OF MESOPOROUS MOLECULAR-SIEVES BY NONIONIC POLYETHYLENE OXIDE SURFACTANTS
    BAGSHAW, SA
    PROUZET, E
    PINNAVAIA, TJ
    [J]. SCIENCE, 1995, 269 (5228) : 1242 - 1244
  • [2] Synthesis of ordered macroporous SiO2 in supercritical CO2 using 3D-latex array templates
    Cabañas, A
    Enciso, E
    Carbajo, MC
    Torralvo, MJ
    Pando, C
    Renuncio, JAR
    [J]. CHEMICAL COMMUNICATIONS, 2005, (20) : 2618 - 2620
  • [3] Degradation of neonicotinoid insecticides by different advanced oxidation processes and studying the effect of ozone on TiO2 photocatalysis
    Cernigoj, Urh
    Stangar, Urska Lavrencic
    Trebse, Polonca
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2007, 75 (3-4) : 229 - 238
  • [4] Coupe RH, 2004, J AM WATER WORKS ASS, V96, P56
  • [5] Preparation of highly ordered titanium dioxide porous films: Characterization and photocatalytic activity
    Doong, Ruey-an
    Chang, Sue-min
    Hung, Yu-chin
    Kao, I-ling
    [J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2007, 58 (01) : 192 - 199
  • [6] PHENYLUREA AND TRIAZINE HERBICIDES IN THE GARONNE RIVER (FRANCE) DURING HIGH FLOOD AND LOW WATER PERIODS
    DUPAS, S
    SCRIBE, P
    ETCHEBER, H
    SALIOT, A
    [J]. INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 1995, 58 (1-4) : 397 - 409
  • [7] A facile route to synthesis of hollow SiO2/Al2O3 spheres with uniform mesopores in the shell wall
    Jiang, YQ
    Ding, XF
    Zhao, JZ
    Hari-Bala
    Zhao, X
    Tian, YM
    Yu, KF
    Sheng, Y
    Guo, YP
    Wang, ZC
    [J]. MATERIALS LETTERS, 2005, 59 (23) : 2893 - 2897
  • [8] Comparison of conventional and mimemulsion copolymerizations of acrylic monomers using poly(vinyl alcohol) as the sole stabilizer
    Kim, N
    Sudol, ED
    Dimonie, VL
    El-Aasser, MS
    [J]. MACROMOLECULES, 2004, 37 (07) : 2427 - 2433
  • [9] KUMARI VD, 2002, APPL CATAL A-GEN, V234, P155
  • [10] Adsorption and degradation of the cationic dyes over Co doped amorphous mesoporous titania-silica catalyst under UV and visible light irradiation
    Li, Junjie
    Liu, Shiqing
    He, Yuyang
    Wang, Jiaqiang
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 115 (03) : 416 - 425