One-step electrodeposited Co and Mn layered double hydroxides on Ni foam for high-performance aqueous asymmetric supercapacitors

被引:25
|
作者
Emin, Adil
Song, Xiaoqiang
Du, Yihe
Chen, Yue
Yang, Mingzhe
Zou, Situo
Fu, Yujun
Li, Junshuai [1 ]
Li, Yali [1 ]
He, Deyan
机构
[1] Lanzhou Univ, LONGi Inst Future Technol, 222 South Tianshui Rd, Lanzhou 730000, Peoples R China
关键词
Aqueous asymmetric supercapacitors; CoMn-LDH; High specific capacitance; High energy density; Long cycle stability; FACILE SYNTHESIS; ENERGY-STORAGE; CARBON CLOTH; NICKEL FOAM; ARRAYS; NANOSHEETS; ARCHITECTURE; NANOFLAKES; NANOWIRES; COMPOSITE;
D O I
10.1016/j.est.2022.104667
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this work, we report a high-performance and self-standing supercapacitor electrode composed of a Co and Mn layered double hydroxide (CoMn-LDH) nanostructure on Ni foam (NF) prepared by one-step electrochemical deposition. The CoMn-LDH electrode delivers a high capacitance of-2673.6 F g(-1) at 1 A g(-1), with the excellent rate performance (-1488.0 F g(-1) at 60 A g(-1)) and good cycle stability (-86.7% capacitance retention after 5000 cycles at 12 A g(-1)). The asymmetric supercapacitors assembled using the cathode of CoMn-LDH, the anode of activated carbon on carbon cloth and the electrolyte of 2.0 M KOH yield an energy density of-97.5 W h kg(-1) at 800.0 W kg(-1), good cycling performance of-89.2% capacitance retention after 5000 cycles at 5 A g(-1) with the Columbic efficiency around 100%. These results indicate that the CoMn-LDH nanostructure on NF is a promising electrode for high-performance energy storage applications.
引用
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页数:7
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