Studies on microwave irradiated Pd/Nb2O5 catalysts:: Effect of palladium chloride precursor on the chlorobenzene hydrodechlorination activity

被引：4

作者：

Gopinath, R ^{[1
]}

Lingaiah, N ^{[1
]}

Suryanarayana, I ^{[1
]}

Prasad, PSS ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Catalysis & Phys Chem Div, Hyderabad 500007, Andhra Pradesh, India

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2003年 / 79卷 / 01期

关键词：

Pd/Nb2O5; hydrodechlorination; microwave irradiation;

D O I：

10.1023/A:1024103600163

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalysts containing 10 wt. % Pd supported on Nb2O5 were prepared by microwave irradiation and conventional electrical heating, using palladium chloride as the precursor for Pd. Whereas higher residual chloride content decreased the activity and stability of the microwave irradiated catalyst, formation of PdO during calcination in air improved the performance of the conventionally heated catalyst. Calcination after microwave irradiation offers the highest activity and stability.

引用

页码：61 / 67

页数：7

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