Highly efficient dehalogenation using hydroxyapatite-supported palladium nanocluster catalyst with molecular hydrogen

被引：61

作者：

Hara, T ^{[1
]}

Mori, K ^{[1
]}

Oshiba, M ^{[1
]}

Mizugaki, T ^{[1
]}

Ebitani, K ^{[1
]}

Kaneda, K ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Mat Engn Sci, Osaka 5608531, Japan

来源：

GREEN CHEMISTRY | 2004年 / 6卷 / 10期

关键词：

D O I：

10.1039/b408185d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hydroxyapatite-supported Pd nanocluster (PdHAP) efficiently catalysed the dehalogenation of various organic halides in the presence of atmospheric molecular hydrogen; chlorobenzene gave benzene in an excellent TON of 10000 for 10 h. Moreover, the dehalogenation of halophenols in aqueous conditions was also achieved.

引用

页码：507 / 509

页数：3

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