A Stable 3d-4f Heterometallic Cluster with Magneto-Optical Activity

被引：11
作者：
Li, Yan [1 ]
Yang, Yan-Duan [1 ]
Ge, Rui [1 ]
Lv, Zhi-Hao [1 ]
Tian, Chong-Bin [2 ]
Wei, Biao-Wen [3 ]
Li, Xin-Xiong [1 ,2 ]
Zhuang, Nai-Feng [1 ]
Zheng, Shou-Tian [1 ]
机构：
[1] Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
[2] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
[3] Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen 518055, Peoples R China
来源：
INORGANIC CHEMISTRY | 2022年 / 61卷 / 23期
关键词：
MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; RARE-EARTH; ENHANCEMENT; RELAXATION; COMPLEXES; SERIES; EU; LN;
D O I：
10.1021/acs.inorgchem.2c00644
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A stable 3d-4f heterometallic cluster, namely, hydroxyquinoline), has been solvothermally synthesized and structurally characterized. The compound exhibits an interesting structure in which a tetrahedron based on 4f ions interpenetrates with a square pyramid based on 3d ions. Besides, a unique intermolecular interaction was found in Dy4Ni5, giving rise to its high stability not only when it is in the solid state but also when it dissolves in organic solvents. In addition, the magnetic behavior of solid Dy4Ni5 and the magneto-optical activity of the Dy4Ni5 solution were also studied.
引用
收藏
页码：8746 / 8751
页数：6
相关论文
共 55 条
[1]   Structural, morphological and magnetic properties of NiFe2O4 nano-particles [J].
Alarifi, A. ;
Deraz, N. M. ;
Shaban, S. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 486 (1-2) :501-506
[2]   Selective Coordination of Self-Assembled Hexanuclear [Ni4Ln2] and [Ni2Mn2Ln2] (Ln = DyIII, TiaiIII, and HoIII) Complexes: Stepwise Synthesis, Structures, and Magnetic Properties [J].
Bhanja, Avik ;
Schulze, Michael ;
Herchel, Radovan ;
Moreno-Pineda, Eufemio ;
Wernsdorfer, Wolfgang ;
Ray, Debashis .
INORGANIC CHEMISTRY, 2020, 59 (24) :17929-17944
[3]   Two types of Ln2Cu2 hydroxo-trimethylacetate complexes with 0D and 1D motifs: synthetic features, structural differences, and slow magnetic relaxation [J].
Bovkunova, Anna A. ;
Bazhina, Evgeniya S. ;
Evstifeev, Igor S. ;
Nelyubina, Yulia V. ;
Shmelev, Maxim A. ;
Babeshkin, Konstantin A. ;
Efimov, Nikolay N. ;
Kiskin, Mikhail A. ;
Eremenko, Igor L. .
DALTON TRANSACTIONS, 2021, 50 (35) :12275-12286
[4]   Heterometallic 3d-4f single molecule magnets containing diamagnetic metal ions [J].
Chakraborty, Amit ;
Goura, Joydeb ;
Kalita, Pankaj ;
Swain, Abinash ;
Rajaraman, Gopalan ;
Chandrasekhar, Vadapalli .
DALTON TRANSACTIONS, 2018, 47 (27) :8841-8864
[5]   Thermal, nonlinear, magnetic and faraday rotation properties of sol-gel diamagnetic glass /NaYF4: Fe, Ho3+: Role of magnetic ions [J].
Chen, Qiuling ;
Li, Zhuangzhuang ;
Miao, Baoji ;
Ma, Qiuhua .
JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 858
[6]   A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni64RE96} for Gas Separation and Magnetic Cooling Applications [J].
Chen, Wei-Peng ;
Liao, Pei-Qin ;
Yu, Youzhu ;
Zheng, Zhiping ;
Chen, Xiao-Ming ;
Zheng, Yan-Zhen .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (32) :9375-9379
[7]   Two-Dimensional Organic Supramolecule via Hydrogen Bonding and π-π Stacking for Ultrahigh Capacity and Long-Life Aqueous Zinc-Organic Batteries [J].
Chen, Yuan ;
Li, Jianyao ;
Zhu, Qin ;
Fan, Kun ;
Cao, Yiqing ;
Zhang, Guoqun ;
Zhang, Chenyang ;
Gao, Yanbo ;
Zou, Jincheng ;
Zhai, Tianyou ;
Wang, Chengliang .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (37)
[8]   A rare earth alloy as a synthetic reagent: contrasting homometallic rare earth and heterobimetallic outcomes [J].
Deacon, GB ;
Forsyth, CM ;
Junk, PC ;
Leary, SG .
NEW JOURNAL OF CHEMISTRY, 2006, 30 (04) :592-596
[9]   Novel rare earth quinolinolate complexes [J].
Deacon, Glen B. ;
Forsyth, Craig M. ;
Junk, Peter C. ;
Kynast, Ulrich ;
Meyer, Gerd ;
Moore, Joanne ;
Sierau, Jennyfer ;
Urbatsch, Aron .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 451 (1-2) :436-439
[10]   C-Term Faraday Rotation in Metallocene Containing Thin Films [J].
Delage-Laurin, Leo ;
Nelson, Zachary ;
Swager, Timothy M. .
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (21) :25137-25142
123456