Freestanding carbon fiber cloth/sulfur composites for flexible room-temperature sodium-sulfur batteries

被引:185
作者
Lu, Qiongqiong [1 ]
Wang, Xinyu [1 ]
Cao, Jun [1 ]
Chen, Chen [1 ]
Chen, Kena [1 ]
Zhao, Zifang [1 ]
Niu, Zhiqiang [1 ]
Chen, Jun [1 ]
机构
[1] Nankai Univ, Coll Chem, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China
关键词
Carbon fiber cloth; Sulfur composite; Room-temperature; Flexible sodium-sulfur batteries; LI-S BATTERIES; LITHIUM ION BATTERIES; HIGH-PERFORMANCE; ELECTRODE MATERIALS; RECHARGEABLE BATTERIES; CATHODE MATERIALS; CELL CHEMISTRY; GRAPHENE; SUPERCAPACITORS; DISCHARGE;
D O I
10.1016/j.ensm.2017.05.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carbon fiber cloth/sulfur (CFC/S) composites were prepared by loading sulfur in the carbon fiber cloth (CFC) that was obtained by carbonizing the renewable cotton cloth. The CFC/S composites are the excellent cathodes of room-temperature sodium- sulfur (RT Na-S) batteries due to their three-dimensional (3D) interconnected network and high electrolyte uptake of 1156%. The CFC/S composite with area sulfur loading of 2 mg cm(-2) displays an initial discharge capacity of 390 mA h g(-1) at 0.1 C ( 1 C=1675 mA g(-1)) and a capacity of 120 mA h g(-1) after 300 cycles with tetra ethylene glycol dimethyl ether liquid electrolyte. Furthermore, since the freestanding CFC/S composites exhibit good flexibility and conductivity, they can serve as the cathodes of flexible RT Na-S batteries. As a proof of concept, the soft-packaged RT Na-S batteries were fabricated. The capacity of soft-packaged RT Na-S batteries can remain stable when the batteries are bent.
引用
收藏
页码:77 / 84
页数:8
相关论文
共 66 条
  • [1] From lithium to sodium: cell chemistry of room temperature sodium-air and sodium-sulfur batteries
    Adelhelm, Philipp
    Hartmann, Pascal
    Bender, Conrad L.
    Busche, Martin
    Eufinger, Christine
    Janek, Juergen
    [J]. BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2015, 6 : 1016 - 1055
  • [2] Building better batteries
    Armand, M.
    Tarascon, J. -M.
    [J]. NATURE, 2008, 451 (7179) : 652 - 657
  • [3] Shuttle suppression in room temperature sodium-sulfur batteries using ion selective polymer membranes
    Bauer, I.
    Kohl, M.
    Althues, H.
    Kaskel, S.
    [J]. CHEMICAL COMMUNICATIONS, 2014, 50 (24) : 3208 - 3210
  • [4] Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]
  • [5] Progress in electrical energy storage system: A critical review
    Chen, Haisheng
    Cong, Thang Ngoc
    Yang, Wei
    Tan, Chunqing
    Li, Yongliang
    Ding, Yulong
    [J]. PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2009, 19 (03) : 291 - 312
  • [6] Scalable Clean Exfoliation of High-Quality Few-Layer Black Phosphorus for a Flexible Lithium Ion Battery
    Chen, Long
    Zhou, Guangmin
    Liu, Zhibo
    Ma, Xiaomeng
    Chen, Jing
    Zhang, Zhiyong
    Ma, Xiuliang
    Li, Feng
    Cheng, Hui-Ming
    Ren, Wencai
    [J]. ADVANCED MATERIALS, 2016, 28 (03) : 510 - +
  • [7] Flexible and wearable wire-shaped microsupercapacitors based on highly aligned titania and carbon nanotubes
    Chen, Tao
    Dai, Liming
    [J]. ENERGY STORAGE MATERIALS, 2016, 2 : 21 - 26
  • [8] A nitrogen doped carbonized metal-organic framework for high stability room temperature sodium-sulfur batteries
    Chen, Yu-Ming
    Liang, Wenfeng
    Li, Si
    Zou, Feng
    Bhaway, Sarang M.
    Qiang, Zhe
    Gao, Min
    Vogt, Bryan D.
    Zhu, Yu
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (32) : 12471 - 12478
  • [9] A Carbon-Cotton Cathode with Ultrahigh-Loading Capability for Statically and Dynamically Stable Lithium-Sulfur Batteries
    Chung, Sheng-Heng
    Chang, Chi-Hao
    Manthiram, Arumugam
    [J]. ACS NANO, 2016, 10 (11) : 10462 - 10470
  • [10] Sulfur-Impregnated Activated Carbon Fiber Cloth as a Binder-Free Cathode for Rechargeable Li-S Batteries
    Elazari, Ran
    Salitra, Gregory
    Garsuch, Arnd
    Panchenko, Alexander
    Aurbach, Doron
    [J]. ADVANCED MATERIALS, 2011, 23 (47) : 5641 - +