Spiral stir bar sorptive extraction with polyaniline-polydimethylsiloxane sol-gel packings for the analysis of trace estrogens in environmental water and animal-derived food samples

被引:24
作者
Fan, Wenying [1 ]
He, Man [1 ]
You, Linna [1 ]
Chen, Beibei [1 ]
Hu, Bin [1 ]
机构
[1] Wuhan Univ, Dept Chem, Minist Educ, Key Lab Analyt Chem Biol & Med, Wuhan 430072, Hubei, Peoples R China
关键词
animal-derived food; estrogens; polyaniline; stir bar sorptive extraction; CHROMATOGRAPHY-MASS SPECTROMETRY; STEROID SEX-HORMONES; LIQUID-CHROMATOGRAPHY; MONOLITHIC MATERIAL; 17-BETA-ESTRADIOL; DERIVATIZATION; ARRAY;
D O I
10.1002/jssc.201900819
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A spiral stir bar was proposed by using stainless steel spring as the extraction phase carrier to avoid the extraction phase friction and increase the amount of extraction phase for improving extraction efficiency. The extraction phase is filled in the cavity of the spring, resulting in a larger amount of the extraction phase than that conventionally coated on glass stir bar or stainless steel wire. Polyaniline-polydimethylsiloxane sol-gel packed spiral stir bar was prepared and evaluated for the extraction of five estrogens. The prepared spiral stir bar presented good extraction efficiency/preparation reproducibility and long lifetime (more than 150 reused times) for target estrogens. Based on it, a method of spiral stir bar sorptive extraction combined with high performance liquid chromatography coupled with ultra-violet detection was developed for the analysis of trace estrogens in environmental and food samples. The detection limit for five estrogens was 0.11-.31 mu g/L, with the enrichment factors of 83.0-118-fold (maximal enrichment factor: 200-fold). The reproducibility evaluated with each estrogen of 5 mu g/L (n = 5) was 5.8-8.9%. The method was successfully applied for the determination of estrogens in environmental water and animal-derived food samples.
引用
收藏
页码:1137 / 1144
页数:8
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