Three-dimensional fivefold interpenetrating microporous metal-organic framework based on mixed flexible ligands

被引：53
|
作者：
Huang, Xiao-Ying [1 ]
Yue, Ke-Fen [1 ]
Jin, Jun-Cheng [1 ]
Liu, Jian-Qiang [1 ]
Wang, Cheng-Jun [1 ]
Wang, Yao-Yu [1 ]
Shi, Qi-Zhen [1 ]
机构：
[1] NW Univ Xian, Coll Chem & Mat Sci, Shaanxi Key Lab Physicoinorgan Chem, Key Lab Synthet & Nat Funct Mol Chem,Minist Educ, Xian 710069, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Interpenetration; Microporous structure; Crystal engineering; Fluorescence spectrum; BUILDING-BLOCKS; CIPROFLOXACIN COMPLEXES; COORDINATION POLYMERS; INTERWOVEN HELICES; NETWORK; MOTIFS; DESIGN; LAYERS;
D O I：
10.1016/j.inoche.2009.12.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The chiral diamondoidlike Cd(II) containing coordination polymer {[Cd(oba)(bib)]2H(2)O}(n) (1) (oba=4.4'-oxybis(benzoate), bib= 1,4-bis(2-methyl-imidazol-1-yl)butane) is reported, the 3D networks interpenetrate fivefold, nevertheless leave cavities capable of including sizable guest molecules. This compound also exhibits high thermal stability and blue-shift emission, and can be explored for potential blue luminescent materials (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码：338 / 341
页数：4
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