Three-dimensional fivefold interpenetrating microporous metal-organic framework based on mixed flexible ligands

被引：53

作者：

Huang, Xiao-Ying ^{[1
]}

Yue, Ke-Fen ^{[1
]}

Jin, Jun-Cheng ^{[1
]}

Liu, Jian-Qiang ^{[1
]}

Wang, Cheng-Jun ^{[1
]}

Wang, Yao-Yu ^{[1
]}

Shi, Qi-Zhen ^{[1
]}

机构：

[1] NW Univ Xian, Coll Chem & Mat Sci, Shaanxi Key Lab Physicoinorgan Chem, Key Lab Synthet & Nat Funct Mol Chem,Minist Educ, Xian 710069, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Interpenetration; Microporous structure; Crystal engineering; Fluorescence spectrum; BUILDING-BLOCKS; CIPROFLOXACIN COMPLEXES; COORDINATION POLYMERS; INTERWOVEN HELICES; NETWORK; MOTIFS; DESIGN; LAYERS;

D O I：

10.1016/j.inoche.2009.12.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chiral diamondoidlike Cd(II) containing coordination polymer {[Cd(oba)(bib)]2H(2)O}(n) (1) (oba=4.4'-oxybis(benzoate), bib= 1,4-bis(2-methyl-imidazol-1-yl)butane) is reported, the 3D networks interpenetrate fivefold, nevertheless leave cavities capable of including sizable guest molecules. This compound also exhibits high thermal stability and blue-shift emission, and can be explored for potential blue luminescent materials (C) 2010 Elsevier B V All rights reserved

引用

页码：338 / 341

页数：4

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