Transition metal catalysed diboration

被引：343

作者：

Marder, TB

Norman, NC

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

TOPICS IN CATALYSIS | 1998年 / 5卷 / 1-4期

关键词：

diboration; hydroboration; boron; platinum; rhodium; palladium; transition metal; homogeneous catalysis; boronate ester; arylboronate; vinylboronate; diboron; borylstannation; borylsilylation; silaboration; silicon; tin;

D O I：

10.1023/A:1019145818515

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Homogeneous transition metal catalysed hydroboration reactions are discussed briefly, providing the background which led to the recent discovery of metal catalysed diborations [additions of the B-B bond in B-2(OR)(4) compounds] of alkynes, alkenes, 1,3-diynes, 1,3-dienes, and alpha,beta-unsaturated ketones. Catalysed additions of B-Si and B-Sn bonds are also presented. Metal catalysed synthesis of organoboron compounds is a useful new synthetic method.

引用

页码：63 / 73

页数：11

共 69 条

[61] Pelter A., 1988, BORANE REAGENTS
[62] Reaction of BX(2)-BX(2) (X=H or OH) with M(PH3)(2) (M=Pd or Pt). A theoretical study of the characteristic features
Sakaki, S
Kikuno, T
[J]. INORGANIC CHEMISTRY, 1997, 36 (02) : 226 - 229
[63] Regio- and stereo-selective silaboration of alkynes catalysed by palladium and platinum complexes
Suginome, M
Nakamura, H
Ito, Y
[J]. CHEMICAL COMMUNICATIONS, 1996, (24) : 2777 - 2778
[64] BORON HETEROCYCLES .V. PREPARATION AND CHARACTERIZATION OF SELECTED HETERONUCLEAR DIBORON RING SYSTEMS
WELCH, CN
SHORE, SG
[J]. INORGANIC CHEMISTRY, 1968, 7 (02) : 225 - &
[65] REACTIONS OF CATECHOLATOBORANE WITH PHOSPHINORHODIUM COMPLEXES - MOLECULAR-STRUCTURES OF [RHHCL(BCAT)(PPRI3)2] AND [((PRI2PCH2)2)RH((ETA-6-CAT)BCAT)] (CAT = 1,2-O2C6H4)
WESTCOTT, SA
TAYLOR, NJ
MARDER, TB
BAKER, RT
JONES, NJ
CALABRESE, JC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (05) : 304 - 305
[66] TRANSITION-METAL-CATALYZED ADDITION OF CATECHOLBORANE TO ALPHA-SUBSTITUTED VINYLARENES - HYDROBORATION VS DEHYDROGENATIVE BORYLATION
WESTCOTT, SA
MARDER, TB
BAKER, RT
[J]. ORGANOMETALLICS, 1993, 12 (03) : 975 - 979
[67] Rhodium catalysed enantioselective hydroboration of alkenylboronic esters with catecholborane
Wiesauer, C
Weissensteiner, W
[J]. TETRAHEDRON-ASYMMETRY, 1996, 7 (01) : 5 - 8
[68] TRANSITION-METAL-PROMOTED REACTIONS OF BORON HYDRIDES .2. SYNTHESIS AND THERMOLYSIS REACTIONS OF ALKENYLPENTABORANES - A NEW SYNTHESIS OF MONOCARBON CARBORANES
WILCZYNSKI, R
SNEDDON, LG
[J]. INORGANIC CHEMISTRY, 1981, 20 (11) : 3955 - 3962
[69] YUAN Z, UNPUB

← 1 2 3 4 5 6 7 →