Transition metal catalysed diboration

被引：343

作者：

Marder, TB

Norman, NC

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

TOPICS IN CATALYSIS | 1998年 / 5卷 / 1-4期

关键词：

diboration; hydroboration; boron; platinum; rhodium; palladium; transition metal; homogeneous catalysis; boronate ester; arylboronate; vinylboronate; diboron; borylstannation; borylsilylation; silaboration; silicon; tin;

D O I：

10.1023/A:1019145818515

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Homogeneous transition metal catalysed hydroboration reactions are discussed briefly, providing the background which led to the recent discovery of metal catalysed diborations [additions of the B-B bond in B-2(OR)(4) compounds] of alkynes, alkenes, 1,3-diynes, 1,3-dienes, and alpha,beta-unsaturated ketones. Catalysed additions of B-Si and B-Sn bonds are also presented. Metal catalysed synthesis of organoboron compounds is a useful new synthetic method.

引用

页码：63 / 73

页数：11

共 69 条

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