Transition metal catalysed diboration

被引：346
作者：
Marder, TB
Norman, NC
机构：
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
来源：
TOPICS IN CATALYSIS | 1998年 / 5卷 / 1-4期
关键词：
diboration; hydroboration; boron; platinum; rhodium; palladium; transition metal; homogeneous catalysis; boronate ester; arylboronate; vinylboronate; diboron; borylstannation; borylsilylation; silaboration; silicon; tin;
D O I：
10.1023/A:1019145818515
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Homogeneous transition metal catalysed hydroboration reactions are discussed briefly, providing the background which led to the recent discovery of metal catalysed diborations [additions of the B-B bond in B-2(OR)(4) compounds] of alkynes, alkenes, 1,3-diynes, 1,3-dienes, and alpha,beta-unsaturated ketones. Catalysed additions of B-Si and B-Sn bonds are also presented. Metal catalysed synthesis of organoboron compounds is a useful new synthetic method.
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页码：63 / 73
页数：11
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