Novel engineering of ruthenium-based electrocatalysts for acidic water oxidation: A mini review

被引：34

作者：

Zhou, Feng ^{[1
]}

Zhang, Lijie ^{[1
]}

Li, Juan ^{[1
]}

Wang, Qi ^{[1
]}

Chen, Yurou ^{[1
]}

Chen, Hailun ^{[1
]}

Lu, Guolong ^{[1
]}

Chen, Guang ^{[1
]}

Jin, Huile ^{[1
]}

Wang, Shun ^{[1
]}

Wang, Jichang ^{[2
]}

机构：

[1] Wenzhou Univ, Inst New Mat & Ind Technol, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China

[2] Univ Windsor, Dept Chem & Biochem, Windsor, ON, Canada

来源：

ENGINEERING REPORTS | 2021年 / 3卷 / 08期

基金：

中国国家自然科学基金; 加拿大自然科学与工程研究理事会;

关键词：

electrocatalysts; oxygen evolution reaction; PEMWEs; ruthenium; OXYGEN EVOLUTION REACTION; HYDROGEN EVOLUTION; HIGH-PERFORMANCE; ACTIVE ELECTROCATALYSTS; SURFACE OXYGEN; RU; EFFICIENT; CATALYST; PEROVSKITE; NANOPARTICLES;

D O I：

10.1002/eng2.12437

中图分类号：

TP39 [计算机的应用];

学科分类号：

081203 ; 0835 ;

摘要：

The oxygen evolution reaction (OER) is pivotally involved in proton exchange membrane water electrolyzers (PEMWEs). However, the commercialized iridium-based catalysts often suffer from severe sluggish kinetics, eventually deteriorating the polarization and overall PEMWEs performance. Therefore, to develop OER electrocatalysts with promising reaction kinetics and high stability is of great significance for PEMWEs. Compared to iridium, the ruthenium-based catalysts possess lower price and higher activity in acidic water oxidation, which promises Ru-based materials to replace the state-of-the-art IrOx. Yet, the less stable ruthenium than iridium impedes its real applications. In this mini review, recent knowledge of feasible engineering strategies for migrating the Ru-based electrocatalysts' stability is summarized. In order to improve performance and durability, basic fundamentals of acidic OER on nanoscale and molecular engineered Ru-based electrocatalysts are briefly introduced. In the end, the challenges and outlook for engineering novel Ru-based electrocatalysts are presented.

引用

页数：22

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