Synthesis and characterization of water stable polymeric metallo organic composite (PMOC) for the removal of arsenic and lead from brackish water

被引:36
作者
Ahmad, Khalil [1 ]
Shah, Habib-Ur-Rehman [1 ]
Nasim, Hafiza Ammara [1 ]
Ayub, Asif [2 ]
Ashfaq, Muhammad [1 ]
Rauf, Abdul [1 ]
Shah, Syed Shoaib Ahmad [1 ,3 ]
Ahmad, Muhammad Mahboob [4 ]
Nawaz, Haq [5 ]
Hussain, Ejaz [1 ]
机构
[1] Islamia Univ Bahawalpur, Inst Chem, Baghdad Ul Jadeed Campus, Bahawalpur 63100, Pakistan
[2] Univ Agr Faisalabad, Dept Chem, Faisalabad, Pakistan
[3] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, Dept Chem, Hefei, Peoples R China
[4] Bahauddin Zakariya Univ, Inst Chem Sci, Multan, Pakistan
[5] Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, CAS Key Lab Engn Plast, Beijing, Peoples R China
关键词
Co-MOF; PANI for arsenic and lead removal; adsorption studies; arsenic and lead decontamination; water purification; ADSORPTIVE REMOVAL; EFFICIENT REMOVAL; GRAPHENE OXIDE; FRAMEWORK; ADSORBENT; KINETICS; ZIF-8; AS(V); RICE;
D O I
10.1080/15569543.2021.1919902
中图分类号
R99 [毒物学(毒理学)];
学科分类号
100405 ;
摘要
In the present study, highly water stable polymeric metallo organic composite (PMOC) has been synthesized and incorporated into water solution for selective adsorption study. For elucidation of structure, FTIR, P-XRD, SEM, and BET techniques were applied. Several factors related to water chemistry and adsorption analysis were also investigated. The maximum adsorption capacity was 1271.33 and 157.11 mg/g for Pb(II) and As(V), respectively. Chemisorption, monolayer adsorption and homogeneous adsorption takes place for adsorptive confiscation of these metals as studied from kinetics. From consequences, it was established that increase in number of active sites can dramatically increase the adsorption capacity of adsorbent.
引用
收藏
页码:577 / 587
页数:11
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