Concomitant polymorphism and conformational polymorphism in diiodobis[1,2-bis(diphenylphosphino)ethane]platinum(II)

被引：19

作者：

Rath, Nigam P. ^{[1
]}

Kumar, V. S. Senthil ^{[1
]}

Janka, Mesfin ^{[1
]}

Anderson, Gordon K. ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem & Biochem, St Louis, MO 63121 USA

来源：

INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 09期

基金：

美国国家科学基金会;

关键词：

polymorphism; conformational differences; hydrogen bonding; networks; X-ray crystal structures;

D O I：

10.1016/j.ica.2007.02.033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title organometallic compound crystallizes in two different polymorphic modifications. The conformational differences between the two crystalline modifications lead to differences in crystal packing and thus result in the formation of the two polymorphic forms. Both structures are stabilized by weak non-covalent interactions. The change in the phenyl ring rotation from one structure to the other results in the formation of two distinct network structures in the dimorphs. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：2997 / 3001

页数：5

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