共 53 条
Cotton aerogels and cotton-cellulose aerogels from environmental waste for oil spillage cleanup
被引:131
作者:
Cheng, Hanlin
[1
]
Gu, Bowen
[1
]
Pennefather, Mark P.
[1
]
Nguyen, Thanh X.
[1
]
Phan-Thien, Nhan
[1
]
Duong, Hai M.
[1
]
机构:
[1] Natl Univ Singapore, Dept Mech Engn, 9 Engn Dr 1,EA 07-08, Singapore 117575, Singapore
关键词:
Cotton fibers;
Cellulose fibers;
Aerogel;
Oil absorption;
Environmental waste;
ORGANIC-SOLVENTS;
HIGHLY EFFICIENT;
MICROFIBRILLATED CELLULOSE;
NANOCELLULOSE AEROGELS;
SELECTIVE ABSORPTION;
NANOFIBRIL AEROGELS;
RECYCLABLE SORBENT;
GRAPHENE OXIDE;
WATER;
ABSORBENTS;
D O I:
10.1016/j.matdes.2017.05.082
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
For the first time, successful fabrication of the cotton aerogels and cotton-cellulose aerogels is achieved using recycled fibers from environmental waste for oil absorption. The pure cotton and cotton-cellulose aerogels are obtained using a cost-effective mixing-blending method with polyamide-epichlorohydrin as strengthening additives. The obtained aerogels are silanized using methyltrimethoxysilane via a facile chemical vapor deposition to endow aerogels with hydrophobic surface. Effects of fiber concentrations and cotton-to-cellulose mass ratio on oil absorption performance in various solvents are also investigated. The cotton aerogel with an initial concentration of 0.25 wt% presents the highest oil absorption capacity over 100 g g(-1). Besides, the cotton/cellulose aerogels also demonstrate good absorption capacity in different pollutant organics. The absorption kinetics of the aerogels with different cotton concentrations are also investigated using pseudo first-order model. Both equilibrium absorption and absorption kinetics demonstrate cotton/cellulose aerogels as promising materials for oil absorption and environmental pollution treatment. [GRAPHICS] .
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页码:452 / 458
页数:7
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