Cotton aerogels and cotton-cellulose aerogels from environmental waste for oil spillage cleanup

被引:131
作者
Cheng, Hanlin [1 ]
Gu, Bowen [1 ]
Pennefather, Mark P. [1 ]
Nguyen, Thanh X. [1 ]
Phan-Thien, Nhan [1 ]
Duong, Hai M. [1 ]
机构
[1] Natl Univ Singapore, Dept Mech Engn, 9 Engn Dr 1,EA 07-08, Singapore 117575, Singapore
关键词
Cotton fibers; Cellulose fibers; Aerogel; Oil absorption; Environmental waste; ORGANIC-SOLVENTS; HIGHLY EFFICIENT; MICROFIBRILLATED CELLULOSE; NANOCELLULOSE AEROGELS; SELECTIVE ABSORPTION; NANOFIBRIL AEROGELS; RECYCLABLE SORBENT; GRAPHENE OXIDE; WATER; ABSORBENTS;
D O I
10.1016/j.matdes.2017.05.082
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
For the first time, successful fabrication of the cotton aerogels and cotton-cellulose aerogels is achieved using recycled fibers from environmental waste for oil absorption. The pure cotton and cotton-cellulose aerogels are obtained using a cost-effective mixing-blending method with polyamide-epichlorohydrin as strengthening additives. The obtained aerogels are silanized using methyltrimethoxysilane via a facile chemical vapor deposition to endow aerogels with hydrophobic surface. Effects of fiber concentrations and cotton-to-cellulose mass ratio on oil absorption performance in various solvents are also investigated. The cotton aerogel with an initial concentration of 0.25 wt% presents the highest oil absorption capacity over 100 g g(-1). Besides, the cotton/cellulose aerogels also demonstrate good absorption capacity in different pollutant organics. The absorption kinetics of the aerogels with different cotton concentrations are also investigated using pseudo first-order model. Both equilibrium absorption and absorption kinetics demonstrate cotton/cellulose aerogels as promising materials for oil absorption and environmental pollution treatment. [GRAPHICS] .
引用
收藏
页码:452 / 458
页数:7
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