[Mo2(O2C-CH3)4•1/2 {(CH2)6N4}•1/2 CH2Cl2] -: a donor-acceptor complex with supramolecular structure

被引：0
|
作者：
Ackermann, H [1 ]
Weller, F [1 ]
Stief, R [1 ]
Dehnicke, K [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2000年 / 626卷 / 07期
关键词：
molybdenum diacetate complex; hexamethylen tetramine; supramolecular structure;
D O I：
10.1002/1521-3749(200007)626:7<1496::AID-ZAAC1496>3.0.CO;2-Q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Yellow single crystals of [Mo-2(O2C-CH3)(4) . 1/2 {(CH2)(6)N-4} . 1/2 CH2Cl2] (1) have been obtained by the reaction of the silylated phosphaneimine Me3SiNPEt3 with [Mo-2(O2C-CH3)(4)] in dichloromethane solution. 1 forms a three-dimensional network with linear N-Mo=Mo-N and tetrahedral (CH2)(6)N4Mo4 moieties, which is topologically related with the PtS type, Space group P4(2)/nnm, Z = 4, lattice dimensions at -70 degrees C: a = b = 1121.7(1), c = 1395.0(3) pm, R-1 = 0.0413.
引用
收藏
页码：1496 / 1498
页数：3
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