[Mo2(O2C-CH3)4•1/2 {(CH2)6N4}•1/2 CH2Cl2] -: a donor-acceptor complex with supramolecular structure

被引：0

作者：

Ackermann, H ^{[1
]}

Weller, F ^{[1
]}

Stief, R ^{[1
]}

Dehnicke, K ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2000年 / 626卷 / 07期

关键词：

molybdenum diacetate complex; hexamethylen tetramine; supramolecular structure;

D O I：

10.1002/1521-3749(200007)626:7<1496::AID-ZAAC1496>3.0.CO;2-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Yellow single crystals of [Mo-2(O2C-CH3)(4) . 1/2 {(CH2)(6)N-4} . 1/2 CH2Cl2] (1) have been obtained by the reaction of the silylated phosphaneimine Me3SiNPEt3 with [Mo-2(O2C-CH3)(4)] in dichloromethane solution. 1 forms a three-dimensional network with linear N-Mo=Mo-N and tetrahedral (CH2)(6)N4Mo4 moieties, which is topologically related with the PtS type, Space group P4(2)/nnm, Z = 4, lattice dimensions at -70 degrees C: a = b = 1121.7(1), c = 1395.0(3) pm, R-1 = 0.0413.

引用

页码：1496 / 1498

页数：3

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